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Spectroscopic analysis of NdMn 2 O 5 by optical and transport mechanism
Applied Physics A ( IF 2.5 ) Pub Date : 2021-04-24 , DOI: 10.1007/s00339-021-04520-x
Hammad Abbas , Syed Hamad Bukhari , Javed Ahmad

The polycrystalline NdMn2O5 multiferroic was synthesized by wet chemistry method followed by heat treatment at 1000 °C. The structure was confirmed by X-ray diffraction (XRD) as orthorhombic with space group Pbam. The particle size and strain were calculated by Williamson-Hall method. Both infrared (IR) active and Raman active phonons have been observed using IR reflectivity and Raman spectroscopies. UV–visible absorption spectrum suggests that a possible optical band Eg ∼ 1.27 eV has been determined using Kubelka–Munk function. Magnetic field (2 T) dependent magnetization at room temperature suggests the paramagnetic nature of present compound. In addition, frequency-dependent dielectric properties (20Hz–30 GHz) indicate variation in dielectric constant, dielectric loss, tangent loss, as well as AC conductivity, in two distinct dielectric responses which are in accord with Debye relaxation model.



中文翻译:

NdMn 2 O 5的光学和输运光谱分析

通过湿化学法合成多晶NdMn 2 O 5多铁,然后在1000℃下进行热处理。通过X射线衍射(XRD)证实该结构为具有空间群Pbam的斜方晶。粒度和应变通过Williamson-Hall法计算。使用红外反射率和拉曼光谱学已观察到红外(IR)有源和拉曼有源声子。紫外可见吸收光谱表明可能存在一个光学带E g使用Kubelka-Munk函数确定了1.27 eV。室温下取决于磁场(2 T)的磁化强度表明本化合物的顺磁性质。此外,与频率相关的介电特性(20Hz–30 GHz)表示介电常数,介电损耗,切线损耗以及交流电导率的变化在两个与Debye松弛模型一致的介电响应中。

更新日期:2021-04-24
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