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Optimization of sorbitan monooleate and γ-Al2O3 nanoparticles as cold-flow improver in B30 biodiesel blend using response surface methodology (RSM)
Journal of Industrial and Engineering Chemistry ( IF 6.1 ) Pub Date : 2021-04-24 , DOI: 10.1016/j.jiec.2021.04.037
Nur Allif Fathurrahman , Cahyo Setyo Wibowo , Mohammad Nasikin , Munawar Khalil

The synergy of sorbitan monooleate (SMO) and γ-Al2O3 nanoparticles, which was prepared via ultrasonic sonochemistry, as cold-flow improvers (CFI) in B30 biodiesel blend is presented in this work. Response surface methodology (RSM) was employed to study the influence of both CFIs on biodiesel's cold-flow properties, i.e., cloud point (CP), cold-filter plugging point (CFPP), filter blocking tendency (FBT), and precipitate. Based on the result, the relationship between CFI and CP's concentration was best expressed with a quadratic model. Meanwhile, two-factor interaction (2FI) models were more suitable for CFPP, FBT, and precipitate. Based on the result, the most optimum concentration of SMO and γ-Al2O3 nanoparticles were achieved at 0.1% w/v and 50 ppm, respectively. At this condition, the predicted values of CP, CFPP, FBT, and precipitate of the sample were 8.52 °C, 6.056 °C, 7.208, and 564 mg/L, respectively. It is believed that SMO's surface-activity and the ability of γ-Al2O3 nanoparticles to form Pickering emulsion were responsible for the inhibition of excessive crystallization of saturated FAME but also enhancing their colloidal stability at low temperature.



中文翻译:

山梨糖醇单油酸酯和优化的γ-Al 2个ö 3纳米颗粒作为在B30生物柴油掺合冷流动改进响应面法(RSM)

山梨醇单油酸酯的(SMO)的协同作用和在γ-Al 2 ö 3个纳米颗粒,其通过超声波声化学制备,如B30生物柴油掺合冷流改进剂(CFI),提出了这项工作。响应面方法(RSM)被用来研究两种CFIs对生物柴油的冷流特性的影响,即浊点(CP),冷滤塞点(CFPP),过滤器阻塞趋势(FBT)和沉淀物。根据结果​​,用二次模型可以最好地表达CFI和CP浓度之间的关系。同时,两因素相互作用(2FI)模型更适合CFPP,FBT和沉淀。基于该结果,SMO和最适宜浓度的γ-Al 2 ö 3分别以0.1%w / v和 50ppm获得纳米颗粒。在这种情况下,CP的预测值,CFPP,FBT,和样品的沉淀物分别为8.52  ℃,6.056  ℃,7.208,和564 毫克/升,分别。据信,SMO的表面活性和γ-Al的能力2个ø 3纳米颗粒以形成皮克林乳液负责饱和FAME的过度结晶,而且在低温下提高它们的胶体稳定性的抑制。

更新日期:2021-05-18
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