Carbon nanotubes (CNTs) and graphene (Gr) are promising materials for flexible transparent conductive films (TCFs) in optoelectronic application because of their exceptional electrical, optical, and mechanical properties. Here, high-quality graphene nanosheets were synthesized by the one-step green method which using natural polyphenols-gallic acid (GA) as the exfoliation medium through high-pressure homogenization; besides, GA molecules can also be used as a non-covalent modifier to obtain GA modified CNTs (GCNTs). Then, the Au decorated Gr/GCNT-PET (Au-Gr/GCNT-PET) TCFs were obtained by a simple spray-coating process. The TCFs exhibited an excellent optoelectronic performance (Rs = 45.6 Ω/sq., T = ca. 80% at 550 nm), relatively flat surface (roughness = 12.43 nm), good bending resistance (the ΔR _{Au-Gr/GCNT-PET TCF}/R₀ was 0.07 after 1000 times bending tests) and strong adhesion (the f_T of all Au-Gr/GCNT PET films was higher than 0.8). Finally, the Au-Gr/GCNT-PET films were used as an anode to prepare flexible green-light OLED devices; the maximum luminance of the Au-Gr/GCNT-PET device was 6554.1 cd/m² at 15V, and the maximum current efficiency was 4.03 cd/A. It confirmed that this type of TCFs has considerable potential application in photovoltaic devices.

碳纳米管（CNTs）和石墨烯（Gr）由于其卓越的电，光和机械性能，在光电应用中是用于柔性透明导电膜（TCF）的有前途的材料。在这里，以天然多酚-没食子酸（GA）为剥离介质，通过高压均质化的一步绿法合成了高质量的石墨烯纳米片。此外，GA分子也可以用作非共价改性剂以获得GA改性的CNT（GCNT）。然后，通过简单的喷涂工艺获得金装饰的Gr / GCNT-PET（Au-Gr / GCNT-PET）TCF。TCF具有出色的光电性能（Rs  = 45.6Ω / sq。，T =约。在550nm处80％），相对平坦的表面（粗糙度= 12.43纳米），良好的耐弯曲性（的ΔR_{的Au-GR / GCNT-PET TCF} / R ₀为0.07 1000之后次弯曲试验）和附着力强（在˚F _Ť的所有Au-Gr / GCNT PET薄膜均高于0.8）。最后，以Au-Gr / GCNT-PET薄膜为阳极制备柔性的绿色OLED器件。在15V下，Au-Gr / GCNT-PET器件的最大亮度为6554.1cd / m ²，最大电流效率为4.03cd / A。已经证实，这种类型的TCF在光伏器件中具有相当大的潜在应用。