Mini-Reviews in Organic Chemistry ( IF 1.9 ) Pub Date : 2021-02-28 , DOI: 10.2174/1570193x17999200504095803 Luis A. Segura-Quezada 1 , Karina R. Torres-Carbajal 1 , Yuvraj Satkar 1 , Kevin A. Juárez Ornelas 1 , Narendra Mali 1 , Dipak B. Patil 1 , Rocío Gámez-Montaño 1 , Juan R. Zapata-Morales 2 , Selene Lagunas-Rivera 1 , Rafael Ortíz-Alvarado 3 , César R. Solorio-Alvarado 1
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Iodine(III)-based reagents have been broadly used in oxidative reactions for structural functionalization with several functional groups. Among the more relevant and useful synthetic transformations using these hypervalent λ3-reagents, the fluorination, chlorination, bromination, as well as the iodination protocols, can be found. Herein, we present some of the most representative oxidative halogenation procedures of arenes, olefins and alkynes dating from the oldest to the more recent advances in the area, highlighting the discovery and application of new iodine(III)-based halogenating species.
中文翻译：
碘（III）试剂介导的芳烃，烯烃和炔烃的氧化卤代反应
基于碘（III）的试剂已广泛用于氧化反应中，以利用几个官能团进行结构官能化。中使用这些高价λ更相关和有用的合成转化3个-reagents，氟化，氯化，溴化，以及碘化协议，都可以找到。在此，我们介绍了最有代表性的芳烃，烯烃和炔烃的氧化卤化方法，该方法可追溯到该地区最古老的到最近的进展，重点介绍了基于碘（III）的新型卤化物质的发现和应用。
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