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Influence of molten salt with or without V2O5 on hot corrosion and high-temperature tribological performance of HVOF-sprayed Ni-based self-lubricating composite coating
Surface & Coatings Technology ( IF 5.3 ) Pub Date : 2021-04-21 , DOI: 10.1016/j.surfcoat.2021.127210
Enkang Hao , Yijing Wang , Xiaoqin Zhao , Meizhen Gao , Jianmin Chen , Yulong An , Fengyuan Yan

The NiCoCrAlYTa/10Ag/5Mo self-adaptive lubricating composite coating was designed and prepared by high velocity oxy-fuel (HVOF) spraying technology, and its hot corrosion and high-temperature tribological behaviors as well as the interaction mechanisms were investigated. A tremendous amount of β-Ag2MoO4 generated on the surface and acted as a lubricant film during friction when the composite coating was oxidized in no salt condition. The oxidizing process would be accelerated while the composite coating was exposed to molten salt mixtures. The boundaries between the reinforcement and matrix phases in the coating were firstly corroded and then produced NiO, Al2O3, Cr2O3 and the other porous oxides. And there was a continuous and protective rich-(Al, Cr) oxide scale on the surface of composite coating after molten 75Na2SO4 + 25NaCl and 75Na2SO4 + 20NaCl + 5V2O5 (wt%) salts corrosion. Besides, the mechanical and tribological properties of the corroded composite coating were improved. Compared to the case in molten Na2SO4-NaCl salt, the composite coating exposed to molten Na2SO4-NaCl-V2O5 salt was corroded more severely but had better mechanical properties and wear resistance.



中文翻译:

含或不含V 2 O 5的熔盐对HVOF喷涂Ni基自润滑复合涂层的热腐蚀和高温摩擦学性能的影响

通过高速氧燃料喷涂技术设计制备了NiCoCrAlYTa / 10Ag / 5Mo自适应润滑复合涂层,研究了其热腐蚀,高温摩擦学行为及其相互作用机理。β-Ag的组合大量2的MoO 4的表面上产生并用作润滑膜摩擦期间,当复合涂层中没有盐条件被氧化。当复合涂层暴露于熔融盐混合物时,将加速氧化过程。首先腐蚀涂层中的增强相和基体相之间的边界,然后生成NiO,Al 2 O 3,Cr 2 O 3和其他多孔氧化物。在熔融的75Na 2 SO 4  + 25NaCl和75Na 2 SO 4  + 20NaCl + 5V 2 O 5(wt%)盐腐蚀后,复合涂层表面存在连续且保护性的富(Al,Cr)氧化皮。此外,腐蚀的复合涂层的机械和摩擦性能得到改善。与熔融的Na 2 SO 4 -NaCl盐相比,暴露于熔融的Na 2 SO 4 -NaCl-V 2 O 5盐的复合涂层腐蚀更严重,但具有更好的机械性能和耐磨性。

更新日期:2021-04-23
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