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LDPE/MWCNT and LDPE/MWCNT/UHMWPE self-reinforced fiber-composite foams prepared via supercritical CO2: A microstructure-engineering property perspective
The Journal of Supercritical Fluids ( IF 3.4 ) Pub Date : 2021-04-20 , DOI: 10.1016/j.supflu.2021.105248
Mohammad Aghvami-Panah , Mahyar Panahi-Sarmad , Amir Abbas Seraji , Seifollah Jamalpour , Seyed Reza Ghaffarian , Chul B. Park

Low-density polyethylene (LDPE)/Multiwall-Carbon-Nanotube (MWCNT) nanocomposites were foamed using supercritical carbon dioxide (CO2). Uniform nanofiller dispersion was assessed by scanning electron microscopy (SEM), rheological measurements, and wide-angle X-ray diffraction (WAXD). By incorporating MWCNTs in the matrix, the average cell size was reduced to less than one-third that of neat foam (from 32.92 to 9.24 µm), and cell density jumped from 0.205 × 109 to 5.26 × 109 cell/cm3. After evaluating the thermal, mechanical, and electrical properties of the nanocomposites and their foams, as well as elucidating the foaming process's role in the crystalline structure, there was a great need to boost the mechanical performance. Hence, ultra-high molecular-weight-polyethylene (UHMWPE) fiber was embedded in the system, which is a reliable reinforcement for, and compatible with, the polyethylene, owing to its basic similarity to the matrix. The electrical conductivity of the solid and foamed materials was greatly improved by the addition of 15 wt% UHMWPE fibers and 1.4 wt% filler.



中文翻译:

通过超临界CO 2制备的LDPE / MWCNT和LDPE / MWCNT / UHMWPE自增强纤维复合泡沫:微观结构工程性质的观点

使用超临界二氧化碳(CO 2)将低密度聚乙烯(LDPE)/多壁碳纳米管(MWCNT)纳米复合材料发泡。通过扫描电子显微镜(SEM),流变学测量和广角X射线衍射(WAXD)评估纳米填料的均匀分散性。通过在基体中掺入MWCNT,平均泡孔尺寸减少到不到纯泡沫的三分之一(从32.92到9.24 µm),泡孔密度从0.205×10 9跃升至5.26×10 9泡孔/ cm 3。在评估了纳米复合材料及其泡沫的热,机械和电性能,并阐明了发泡过程在晶体结构中的作用后,非常需要提高机械性能。因此,将超高分子量聚乙烯(UHMWPE)纤维嵌入系统中,由于它与基质的基本相似性,因此是聚乙烯的可靠增强材料并与聚乙烯兼容。通过添加15 wt%的UHMWPE纤维和1.4 wt%的填料,可以大大提高固体和泡沫材料的电导率。

更新日期:2021-04-23
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