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The crystal structure and redefinition of utahite
Mineralogy and Petrology ( IF 1.4 ) Pub Date : 2021-04-17 , DOI: 10.1007/s00710-021-00746-y
Owen P. Missen , Stuart J. Mills , Michael S. Rumsey , Malcolm E. Back , Veronica E. Di Cecco , William D. Birch , John Spratt

Utahite was first described in 1997 based mainly on powder X-ray diffraction data and electron microprobe data. No crystal structure was reported. The re-examination of utahite using single-crystal X-ray diffraction and electron microprobe analysis has shown that utahite contains essential Mg, along with Cu, Zn, Te, O and H. The missing MgO was originally attributed to additional H2O. The redefinition of utahite to MgCu2+4Zn2Te6+3O14(OH)4·6H2O from Cu2+5Zn3(Te6+O4)4(OH)8·7H2O has been accepted by the IMA–CNMNC, Proposal 20-C. Utahite is triclinic, crystallising in P\(\overline{1}\) with the unit-cell parameters a = 5.6831(4) Å, b = 8.7793(6) Å, c = 9.9818(9) Å, α = 95.415(7)°, β = 104.129(7)°, γ = 90.098(6)° and V = 480.65(7) Å3, in good agreement with the original study. Utahite features a new framework arrangement of Cuφ6 octahedra, Znφ4 tetrahedra and Teφ6 octahedra (where φ = O or OH), with Mg(H2O)6 octahedra occupying the channel space. Two-thirds of the Te sites form Te6 +2O10 dimers and one third form [Te6+O4(OH)2]4− octahedra, spatially separated from other Te6+ sites. Although unique, the structural framework of utahite is similar to that of leisingite, with both minerals having layers composed of Cuφ6 and Teφ6 octahedra with Mg(H2O)6 octahedra in the interlayer space; however leisingite does not contain Zn. New Raman spectroscopic data is also reported for utahite.



中文翻译:

犹他石的晶体结构与重定义

首次以粉末X射线衍射数据和电子微探针数据为基础,于1997年首次对犹他石进行了描述。没有晶体结构的报道。使用单晶X射线衍射和电子探针分析对铀矿的重新检查表明,铀矿包含必需的Mg以及Cu,Zn,Te,O和H.丢失的MgO最初归因于额外的H 2 O.从U 2到Cu 2+ 5 Zn 3(Te 6+ O 44(OH)8重新定义Utahite为MgCu 2+ 4 Zn 2 Te 6+ 3 O 14(OH)4 ·6H 2 O·7H 2 O具有被IMA-CNMNC接受,提议20-C。犹他州是三斜晶,在P \(\ overline {1} \)中结晶,晶胞参数a  = 5.6831(4)Å,b  = 8.7793(6)Å,c  = 9.9818(9)Å,α  = 95.415( 7)°,β  = 104.129(7)°,γ  = 90.098(6)°和V  = 480.65(7)3,在与原来的研究吻合。Utahite设有Cuφ的一个新的框架结构6八面体,Znφ 4四面体和Teφ 6八面体(其中,φ= O或OH),用Mg(H 2 O)6八面体占据了通道空间。Te位置的三分之二形成Te 6 + 2 O 10二聚体,三分之一形成[Te 6+ O 4(OH)2 ] 4-八面体,与其他Te 6+位置在空间上分开。虽然独特,utahite的结构框架是类似于leisingite的,与具有Cuφ构成的层既矿物质6和Teφ 6用Mg八面体(H 2 O)6八面体在层间空间中; 然而,绿铅矿不含锌。还报道了关于utahite的新的拉曼光谱数据。

更新日期:2021-04-18
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