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Comparison of short-range order in irradiated dysprosium titanates
npj Materials Degradation ( IF 6.6 ) Pub Date : 2021-04-16 , DOI: 10.1038/s41529-021-00165-6
Roman Sherrod , Eric C. O’Quinn , Igor M. Gussev , Cale Overstreet , Joerg Neuefeind , Maik K. Lang

The structural response of Dy2TiO5 oxide under swift heavy ion irradiation (2.2 GeV Au ions) was studied over a range of structural length scales utilizing neutron total scattering experiments. Refinement of diffraction data confirms that the long-range orthorhombic structure is susceptible to ion beam-induced amorphization with limited crystalline fraction remaining after irradiation to 8 × 1012 ions/cm2. In contrast, the local atomic arrangement, examined through pair distribution function analysis, shows only subtle changes after irradiation and is still described best by the original orthorhombic structural model. A comparison to Dy2Ti2O7 pyrochlore oxide under the same irradiation conditions reveals a different behavior: while the dysprosium titanate pyrochlore is more radiation resistant over the long-range with smaller degree of amorphization as compared to Dy2TiO5, the former involves more local atomic rearrangements, best described by a pyrochlore-to-weberite-type transformation. These results highlight the importance of short-range and medium-range order analysis for a comprehensive description of radiation behavior.



中文翻译:

辐照钛酸short的短程有序比较

利用中子全散射实验研究了Dy 2 TiO 5氧化物在快速重离子辐照下(2.2 GeV Au离子)在结构长度范围内的结构响应。衍射数据的细化证实,长距离正交晶体结构易于受到离子束诱导的非晶化作用,在辐照至8×10 12 离子/ cm 2后仍保留有限的结晶度。相反,通过成对分布函数分析检查的局部原子排列,仅显示出辐照后的细微变化,并且仍然由原始的正交结构模型来最好地描述。与Dy 2 Ti 2 O 7的比较在相同照射条件下的烧绿石氧化物显示出不同的行为:尽管与Dy 2 TiO 5相比,钛酸dy烧绿石在长距离上具有更强的抗辐射性,且非晶化程度较小,但前者涉及更多的局部原子重排,最好用烧绿石转变为韦伯石型。这些结果突出了短程和中程分析对于辐射行为的全面描述的重要性。

更新日期:2021-04-16
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