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Enhanced electrocaloric effect at room temperature in Mn 2+ doped lead-free (BaSr)TiO 3 ceramics via a direct measurement
Journal of Advanced Ceramics ( IF 18.6 ) Pub Date : 2021-04-15 , DOI: 10.1007/s40145-020-0450-1
Xiang Niu , Xiaodong Jian , Xianyi Chen , Haoxuan Li , Wei Liang , Yingbang Yao , Tao Tao , Bo Liang , Sheng-Guo Lu

(Ba1−xSrx)(MnyTi1−y)O3 (BSMT) ceramics with x = 35, 40 mol% and y = 0, 0.1, 0.2, 0.3, 0.4, 0.5 mol% were prepared using a conventional solid-state reaction approach. The dielectric and ferroelectric properties were characterized using impedance analysis and polarization-electric field (PE) hysteresis loop measurements, respectively. The adiabatic temperature drop was directly measured using a thermocouple when the applied electric field was removed. The results indicate that high permittivity and low dielectric losses were obtained by doping 0.1–0.4 mol% of manganese ions in (BaSr)TiO3 (BST) specimens. A maximum electrocaloric effect (ECE) of 2.75 K in temperature change with electrocaloric strength of 0.55 K·(MV/m)1 was directly obtained at ∼21 °C and 50 kV/cm in Ba0.6Sr0.4Mn0.001Ti0.999O3 sample, offering a promising ECE material for practical refrigeration devices working at room temperature.



中文翻译:

通过直接测量,在室温下增强了Mn 2+掺杂的无铅(BaSr)TiO 3陶瓷的电热效应

使用x射线制备(Ba 1- x Sr x)(Mn y Ti 1- y)O 3(BSMT)的x = 35、40 mol%和y = 0、0.1、0.2、0.3、0.4、0.5 mol%的陶瓷。常规的固态反应方法。使用阻抗分析和极化电场(P E)磁滞回线测量。当去除施加的电场时,使用热电偶直接测量绝热温度降。结果表明,通过在(BaSr)TiO 3(BST)样品中掺杂0.1–0.4 mol%的锰离子,可以获得高介电常数和低介电损耗。在0.55的K电热强度·(MV / m)的温度变化2.75 k的最大电热效应(ECE)- 1直接在Ba中~21℃和50千伏/厘米得到0.60.4的Mn 0.0010.999 ö 3个样本,为在室温下工作的实用制冷设备提供了一种有希望的ECE材料。

更新日期:2021-04-15
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