Fusion Engineering and Design ( IF 1.9 ) Pub Date : 2021-04-13 , DOI: 10.1016/j.fusengdes.2021.112555 M. Khalid Hossain , K. Kawaguchi , K. Hashizume
Due to the higher hydrogen solubility and diffusivity, gadolinium sesquioxide (Gd2O3) could be expected as a proton conductive material. In this study, monoclinic Gd2O3 was used to evaluate the possible proton conductivity in Ar (), Ar+4% H2 (), Ar+4% D2 (), Ar+H2O (), Ar+D2O (), and O2 () atmospheres in the temperature range from 500°C to 1000°C, to understand its possible application in the DT fuel system of a nuclear fusion reactor. At all temperatures, the conductivity was lower than that of the . Similarly, the was always lower than that of the . The isotope dependence was appreciable at higher temperatures, indicating that Gd2O3 is a proton-conductive oxide at elevated temperatures. However, much improvement is required for the use of Gd2O3 in the DT fuel recovery, analysis, and purification system of fusion reactors.
中文翻译:
倍半氧化g中质子传导性的同位素效应
由于较高的氢溶解度和扩散性,倍半氧化g(Gd 2 O 3)有望作为质子传导材料。在这项研究中,单斜Gd 2 O 3用于评估Ar中可能的质子电导率(),Ar + 4%H 2(),Ar + 4%D 2(),Ar + H 2 O(),Ar + D 2 O()和O 2()温度范围在500°C至1000°C之间,以了解其在核聚变反应堆DT燃料系统中的可能应用。在所有温度下,电导率 低于 。同样, 总是低于 。同位素依赖性在较高温度下是明显的,表明Gd 2 O 3在升高的温度下是质子传导性氧化物。但是,在聚变反应堆的DT燃料回收,分析和纯化系统中使用Gd 2 O 3需要进行很大的改进。