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Purification of benzene-laden air by static adsorption of benzene onto activated carbon prepared from Diplotaxis acris biomass
Biomass Conversion and Biorefinery ( IF 3.5 ) Pub Date : 2021-04-14 , DOI: 10.1007/s13399-021-01462-5
Mohammed Abd El-Samea El-Hashemy , Nasser Fahad Alotaibi

Activated carbon (AC) was prepared from Diplotaxis acris biomass. The change in the surface functional groups between the biomass raw material and the produced AC was detected using Fourier-transform infrared (FTIR) and Raman spectroscopy. The thermal stability of the prepared AC was determined by using thermogravimetric analysis (TGA). It has a surface area of 40.21 m2/g which gave evidence for its external porous surface. The surface porosity and the graphite properties of the prepared AC were detected by scanning electron microscope (SEM) and X-ray diffraction (XRD) analysis, respectively. The amount of adsorbed benzene on the AC surface was determined using a gas chromatograph supported with a flame ionization detector (GC-FID) after extraction in methanol. The adsorption capacity of benzene was 5.4 mg/g at room temperature (25°C), and its removal efficiency reached 95.58% for low benzene concentration (1000 mg/m3). The obtained results were well fitted by the Langmuir isotherm model. The adsorption kinetics of benzene followed the pseudo-second-order kinetic model accompanied by the intra-particle diffusion model. The reuse of the AC samples for three consecutive cycles retained the removal efficiency by more than 75% of its original efficiency. Overall, the study revealed that the prepared AC from Diplotaxis acris biomass has a great potential in the removal of benzene from polluted air.



中文翻译:

通过将苯静态吸附到由Diplotaxis acris生物质制备的活性炭上来净化含苯空气

活性炭(AC)由Diplotaxis acris生物质制备。使用傅立叶变换红外(FTIR)和拉曼光谱法检测生物质原料和生成的AC之间的表面官能团的变化。制备的AC的热稳定性通过热重分析(TGA)确定。它的表面积为40.21 m 2/ g为其外部多孔表面提供了证据。通过扫描电子显微镜(SEM)和X射线衍射(XRD)分析分别检测所制备的AC的表面孔隙率和石墨性质。在甲醇中萃取后,使用配备有火焰离子化检测器(GC-FID)的气相色谱仪确定AC表面上的苯吸附量。室温(25°C)下苯的吸附容量为5.4 mg / g,低苯浓度(1000 mg / m 3)时苯的去除率达到95.58%)。Langmuir等温线模型很好地拟合了获得的结果。苯的吸附动力学遵循伪二级动力学模型,并伴随着颗粒内扩散模型。AC样品连续三个循环重复使用,去除效率保持了其原始效率的75%以上。总体而言,该研究表明,用双线拟南芥生物质制得的AC具有从污染空气中去除苯的巨大潜力。

更新日期:2021-04-14
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