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Thermolysis of Calcium Iodate: Kinetic Parameters
International Journal of Self-Propagating High-Temperature Synthesis ( IF 0.5 ) Pub Date : 2021-04-13 , DOI: 10.3103/s1061386221010076 Yu. M. Maksimov , A. M. Shulpekov , A. N. Avramchik , B. Sh. Braverman
中文翻译:
碘酸钙的热解:动力学参数
更新日期:2021-04-13
International Journal of Self-Propagating High-Temperature Synthesis ( IF 0.5 ) Pub Date : 2021-04-13 , DOI: 10.3103/s1061386221010076 Yu. M. Maksimov , A. M. Shulpekov , A. N. Avramchik , B. Sh. Braverman
Abstract
Thermal transformations in calcium iodate were studied by differential scanning calorimetry in the temperature range of 300–973 K. The process was found to proceed by the scheme: Ca(IO3)2∙H2O → Ca(IO3)2 → Ca5(IO6)2 + I2 + 9O2. Calculated kinetic parameters adequately described experiment. X-ray diffraction patterns of the intermediate products formed at 523, 723, and 873 K well agreed with the available literature data.
中文翻译:
碘酸钙的热解:动力学参数
摘要
通过差示扫描量热法在300–973 K的温度范围内研究了碘酸钙的热转化。发现该过程按以下方案进行:Ca(IO 3)2 ∙H 2 O→Ca(IO 3)2 →Ca 5(IO 6)2 + I 2 + 9O 2。计算的动力学参数充分描述了实验。在523、723和873 K处形成的中间产物的X射线衍射图与现有文献数据完全吻合。