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Solar-light induced photoreduction of CO2 using nonthermal plasma sulfurized MoO3@MoS2-CuS composites
Journal of Environmental Chemical Engineering ( IF 7.4 ) Pub Date : 2021-04-09 , DOI: 10.1016/j.jece.2021.105469
Xiaogang Zheng , Yang Li , Hao Peng , Jing Wen

To enhance the solar-light photocatalytic efficiency of MoO3 for conversion of CO2 into CH4 and CO, CuS and MoS2 co-modified h-MoO3 (MoO3@MoS2-CuS) composites were sulfurized by dielectric barrier discharge (DBD) plasma. The photocatalytic activities of MoO3@MoS2 and MoO3@MoS2-CuS for solar-light driven CO2 photoreduction were better than that of h-MoO3, while MoO3@MoS2-CuS presented the enhancing CH4 yield and the declining CO yield. It’s ascribed to the improved visible light response and the efficient charge transfer and separation. In addition, CO2 and H2O molecules were trapped and photo-reduced at the naked edge-rich sites of junction interface between MoO3, MoS2, and CuS. The optimal MoO3@MoS2-CuS-3 with the CuS content of 2.27 wt% presented the CH4 yield of 44.64 μmol g-1 h-1 and CO yield of 7.59 μmol g-1 h-1, and its durability was slightly declined after three cycles.



中文翻译:

太阳光诱导的非热等离子体硫化MoO 3 @MoS 2 -CuS复合材料对CO 2的光还原

为了提高MoO 3的太阳光光催化效率,以将CO 2转化为CH 4和CO,通过介电势垒放电将CuS和MoS 2共改性的h-MoO 3(MoO 3 @MoS 2 -CuS)复合材料硫化( DBD)等离子。的MoO的光催化活性3个@MoS 2和的MoO 3 @MoS 2 -CuS太阳能光驱动的CO 2光还原比使得h-的MoO的更好3,而的MoO 3个@MoS 2 -CuS呈现的提高CH 4收率和下降的一氧化碳收率。这归因于改善的可见光响应以及有效的电荷转移和分离。此外,CO 2和H 2 O分子在MoO 3,MoS 2和CuS之间的结界面的裸露的富边位置处被捕获并被光还原。CuS含量为2.27 wt%的最佳MoO 3 @MoS 2 -CuS-3 的CH 4产率为44.64μmolg -1 h -1,CO产率为7.59μmolg -1 h -1,其耐久性为经过三个周期后略有下降。

更新日期:2021-04-09
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