Organocatalytic aminocarbonylation of α,β-unsaturated ketones with N,N-dimethyl carbamoylsilane,New Journal of Chemistry

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Organocatalytic aminocarbonylation of α,β-unsaturated ketones with N,N-dimethyl carbamoylsilane
New Journal of Chemistry ( IF 3.3 ) Pub Date : 2021-3-19 , DOI: 10.1039/d1nj00782c
Shou-Shan Yang _{1,

2,

3,

4,

5} , Ying-Zheng Ren _{1,

2,

3,

4,

5} , Yu-Yu Guo _{1,

2,

3,

4,

5} , Guang-Fen Du _{1,

2,

3,

4,

5} , Zhi-Hua Cai _{1,

2,

3,

4,

5} , Lin He _{1,

2,

3,

4,

5}

Affiliation

An organic superbase-catalyzed aminocarbonylation reaction of α,β-unsaturated ketones was reported. Under the catalysis of 10 mol% Schwesinger's superbase t-Bu-P₄, a variety of enones and ynones reacted with N,N-dimethyl carbamoylsilane to afford α-siloxyamides or α-hydroxyamides in 56–82% yields.

中文翻译：

N，N-二甲基氨基甲酰基硅烷对α，β-不饱和酮的有机催化氨基羰基化

报道了有机超碱催化的α，β-不饱和酮的氨基羰基化反应。在10 mol％Schwesinger的超碱t -Bu-P ₄的催化下，各种烯酮和ynones与N，N-二甲基氨基甲酰基硅烷反应，以56-82％的产率提供α-甲硅烷氧基酰胺或α-羟基酰胺。

更新日期：2021-04-09

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