Abstract

The synthesis of polyamides containing lateral sulfonyl chloride groups is proposed. The presented polymers can serve as macroinitiators for preparing thermosensitive polyoxazolines. It is proved that polymerization with multisulfochloride initiators proceeds without irreversible termination reaction and makes it possible to obtain polymers with a fairly narrow molecular weight distribution.

中文翻译：

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磺酰氯型大分子引发剂合成聚酰胺-接枝-聚恶唑啉

摘要

提出了含有侧磺酰氯基团的聚酰胺的合成。提出的聚合物可以用作制备热敏性聚恶唑啉的大分子引发剂。业已证明，用多氯化硫引发剂进行的聚合反应不会发生不可逆的终止反应，并有可能获得分子量分布相当窄的聚合物。