Journal of Cluster Science ( IF 2.7 ) Pub Date : 2021-04-08 , DOI: 10.1007/s10876-021-02056-x Yevhen Kalishyn , Igor Bychko , Tetyana Kameneva , Olexander Skoblik , Yevhen Polunkin , Peter Strizhak
This work shows the inhibition property of the α-FeOOH nanoparticles on the oxidation reactions. The structure of the nanoparticles is confirmed by elemental analysis, FTIR, Mössbauer spectroscopy, TEM, and oxygen titration. We reveal that the α-FeOOH nanoparticles drastically inhibit the benzyl alcohol chain oxidation. The inhibition of the benzyl alcohol oxidation by the α-FeOOH nanoparticles is caused by the reactions between the nanoparticles and peroxyl radicals. Our finding suggests that the α-FeOOH nanoparticles may be used as an effective additive to preserve organic compounds from oxidation. Particularly, we illustrate that the α-FeOOH nanoparticles enhance the storage properties of motor fuel. The inhibition efficiency of the α-FeOOH nanoparticles may result in a variety of new applications of iron-containing nanoscale materials.
中文翻译:
α-FeOOH纳米粒子在苄醇氧化中的抑制作用
这项工作表明了α-FeOOH纳米粒子对氧化反应的抑制性能。纳米颗粒的结构通过元素分析,FTIR,Mössbauer光谱,TEM和氧滴定确定。我们发现,α-FeOOH纳米颗粒可显着抑制苄醇链的氧化。α-FeOOH纳米粒子对苯甲醇氧化的抑制是由纳米粒子与过氧自由基之间的反应引起的。我们的发现表明,α-FeOOH纳米颗粒可以用作有效的添加剂,以防止有机化合物氧化。特别地,我们说明了α-FeOOH纳米颗粒增强了汽车燃料的储存性能。α-FeOOH纳米粒子的抑制效率可能导致含铁纳米级材料的各种新应用。