Synthesis of the enantiomers of 13‐methylheptacosane, the sex pheromone of pear psylla, Cacopsylla pyricola,Chirality

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Synthesis of the enantiomers of 13‐methylheptacosane, the sex pheromone of pear psylla, Cacopsylla pyricola
Chirality ( IF 2.8 ) Pub Date : 2021-04-06 , DOI: 10.1002/chir.23307
Gucheng Yuan ₁ , Yuxiong Yang ₁ , Jiawei Liu ₁ , Qinghua Bian ₁ , Min Wang ₁ , Jiangchun Zhong ₁

Affiliation

An efficient and gram‐scale enantioselective synthesis of (R)‐ and (S)‐13‐methylheptacosane, the sex pheromone of pear psylla, has been developed. The key steps of the approach included Evans' chiral auxiliaries and Wittig coupling of chiral phosphonium salt with aldehyde.

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