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Persistence, dissipation behavior and dietary risk assessment of a combi-product of chlorantraniliprole and λ-cyhalothrin in/on pigeonpea (Cajanus cajan L.)
Heliyon ( IF 3.4 ) Pub Date : 2021-04-06 , DOI: 10.1016/j.heliyon.2021.e06377
Rohan V. Kansara , Vanrajsinh H. Solanki , Susheel Singh , Digvijaysinh Chauhan

Pigeonpea (Cajanus cajan L.) is an annually cultivated food and forage crop, attacked by a large number of pests mainly pod borer (Helicoverpa armigera). For the control of this insect pest, a combination of broad-spectrum insecticides viz., chlorantraniliprole and λ-cyhalothrin have been in use to reduce the pod damage and increase crop production worldwide. Therefore, a field trial was conducted to study dissipation and persistence behavior of insecticides combination (Chlorantraniliprole 9.26 % + λ-cyhalothrin 4.63 % ZC) in/on pigeonpea at the recommended dose (RD) 30 g a.i./ha and double recommended dose 60 g a.i./ha (2RD). The quantitative analysis was performed using ultra-high performance liquid chromatography tandem mass spectrometry (UHPLC-MS/MS) for chlorantraniliprole and Gas chromatography with electron captured detector (GC-ECD) for λ-cyhalothrin. The Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) method was validated for its accuracy, precision and sensitivity. The chlorantraniliprole persisted upto 30 days and λ-cyhalothrin persisted upto 10 days at RD and 20 days at 2RD. The half-lives (DT50) of chlorantraniliprole and λ-cyhalothrin were from 4.95 to 5.78 days and 2.48–4.33 days at recommended and double recommended dose in pigeonpea, respectively. However, residues of both insecticides measured from soil at 30th day and harvest time were below the limit of quantification (LOQ). The waiting period deciphered for chlorantraniliprole and λ-cyhalothrin applied as combi-product was 9 days at recommended dose. Dietary risk assessment (Risk quotient<1) was performed on the basis of field trial suggested the application of chlorantraniliprole and λ-cyhalothrin as combi-product at recommended dose is safe for the consumers.



中文翻译:

持久性,散热性能和木豆氯虫苯甲酰胺和λ三氯氟氰菊酯在/的组合式产品的膳食风险评估(木豆L.)

木豆(Cajanus cajan L.)是一种每年种植的粮食和饲料作物,主要受荚虫(Helicoverpa armigera)的害虫侵袭。为了控制这种害虫,使用了广谱杀虫剂的组合,氯蒽醌和λ-氯氟氰菊酯已被用于减少豆荚的损害并提高全世界的农作物产量。因此,进行了一项田间试验,研究了在推荐剂量(RD)30 g ai / ha和两倍推荐剂量60 g的木豆中/上使用杀虫剂组合(氯吡虫啉9.26%+λ-氯氟氰菊酯4.63%ZC)的消散和持久性行为。 ai / ha(2RD)。定量分析是使用超高效液相色谱串联质谱法(UHPLC-MS / MS)进行氯氰菊酯的分析和气相色谱用电子捕获检测器(GC-ECD)进行的氯氟氰菊酯的分析。快速,简便,便宜,有效,坚固和安全(QuEChERS)方法经过验证,具有准确性,精密度和灵敏性的特点。氯氰菊酯在RD持续30天,而氟氰菊酯在RD持续10天,在2RD持续20天。半衰期(DT50氯虫苯甲酰胺和λ三氯氟氰菊酯)分别为从4.95到5.78天和2.48-4.33天在推荐和双推荐剂量在木豆,。但是,在30天和收获时间从土壤中测得的两种杀虫剂的残留量均低于定量限(LOQ)。推荐的剂量下,氯尿嘧啶和λ-氯氟氰菊酯作为组合产品应用的等待时间为9天。饮食风险评估(风险商<1)是在田间试验的基础上进行的,表明以建议的剂量联合使用扑虫腈和λ-氯氟氰菊酯作为推荐产品对消费者而言是安全的。

更新日期:2021-04-08
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