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Thermal Plasma Synthesis of Li 2 S Nanoparticles for Application in Lithium-Sulfur Batteries
Plasma Chemistry and Plasma Processing ( IF 2.6 ) Pub Date : 2021-04-03 , DOI: 10.1007/s11090-021-10168-5
J. Nava-Avendaño , M. Nussbaum , J. Veilleux

Inductively-coupled thermal plasma processes were used to produce nanosized Li2S. Prior to the syntheses, the feasibility of forming Li2S was first evaluated using FactSage by considering the phase diagrams of sulfur and different lithium precursors in reducing atmospheres; Li2O, LiOH·H2O, Li2CO3 and Li2SO4·H2O all showed promises in producing Li2S nanoparticles, as confirmed by experiments. Argon and hydrogen mixtures were used as plasma gases, and a carbothermal reduction was implemented for Li2SO4·H2O. In addition, carbon-coated Li2S nanoparticles were synthesized with downstream injection of methane. Carbon was shown to stabilize Li2S upon contact with ambient air. The Li2S nanoparticles were electrochemically tested in half-cells using electrolytes containing LiNO3 or Li2S6 as additives. It was found that adding LiNO3 to the electrolyte was detrimental to the electrochemical performance of Li2S, whereas the combination of Li2S6 and LiNO3 as additives doubled the charge and discharge capacities of the half-cell over 10 cycles.



中文翻译:

Li 2 S纳米粒子的热等离子体合成在锂硫电池中的应用

使用感应耦合的热等离子体工艺来制备纳米栗2 S.在此之前的合成,形成Li的可行性2 S为使用第一评价FACTSAGE通过考虑硫和在还原性气氛不同锂前体的相图; 实验证实,Li 2 O,LiOH·H 2 O,Li 2 CO 3和Li 2 SO 4 ·H 2 O均显示出生产Li 2 S纳米颗粒的希望。使用氩气和氢气的混合物作为等离子体气体,并对Li 2 SO 4 ·H进行碳热还原2 O.此外,在下游注入甲烷的情况下合成了碳包覆的Li 2 S纳米粒子。碳显示出稳定栗2在与周围空气接触S上。使用含有LiNO 3或Li 2 S 6作为添加剂的电解质在半电池中对Li 2 S纳米粒子进行了电化学测试。发现向电解质中添加LiNO 3不利于Li 2 S的电化学性能,而Li 2 S 6和LiNO 3作为添加剂的组合在10个循环中使半电池的充电和放电容量增加了一倍。

更新日期:2021-04-04
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