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Influence of Hardening Additives on the Characteristics of the Tribological TiC–Al 2 O 3 Ceramic Composite Obtained by SHS
Refractories and Industrial Ceramics ( IF 0.4 ) Pub Date : 2021-04-01 , DOI: 10.1007/s11148-021-00515-6
D. H. A. Besisa , Z. I. Zaki , A. M. M. Amin , Y. M. Z. Ahmed , E. M. M. Ewais

Addition of various reinforcements was studied in an attempt to produce a TiC–Al2O3 composite with high density, homogeneous microstructure, and outstanding mechanical properties for use in aggressive media using self-propagating high-temperature synthesis (SHS). Ductile Ni-metal powder (5 – 20 wt.%) and Al2O3 and ZrO2 (1 mole fraction) dilutions with and without Ni addition were introduced into TiC–Al2O3 composite synthesized by combined SHS and direct consolidation (DC). The influence of the Ni content and dilution with Al2O3 and ZrO2 on the phase composition, densification behavior, microstructure, and mechanical properties of the synthesized TiC–Al2O3 composite was investigated. The best results were obtained by adding Ni(5 wt.%) to the TiC–Al2O3 composite. However, the chemical reactions between the starting precursors were disturbed and the composite characteristics worsened if the Ni content was increased to >5 wt.%. Accordingly, addition of 5 wt.% Ni was suggested to produce a highly dense TiC–Al2O3 composite with a homogenized morphology and unparalleled mechanical properties. Moreover, the produced composites could be used successfully in aggressive media and tribological applications.



中文翻译:

硬化添加剂对SHS获得的摩擦学TiC–Al 2 O 3陶瓷复合材料性能的影响

为了生产具有高密度,均匀的微观结构和出色的机械性能的TiC–Al 2 O 3复合材料,研究了各种增强材料的应用,这些材料可通过自蔓延高温合成(SHS)用于腐蚀性介质。将韧性镍金属粉末(5-20​​ wt。%)和Al 2 O 3和ZrO 2(1摩尔分数)稀释液在添加和不添加镍的情况下引入到通过结合SHS和直接固结合成的TiC–Al 2 O 3复合材料中( DC)。Ni含量和Al 2 O 3和ZrO 2稀释的影响对合成的TiC–Al 2 O 3复合材料的相组成,致密化行为,微观结构和力学性能进行了研究。通过将Ni(5 wt。%)添加到TiC–Al 2 O 3复合材料中可获得最佳结果。然而,如果Ni含量增加至> 5wt。%,则起始前体之间的化学反应受到干扰并且复合特性恶化。因此,建议添加5 wt。%的Ni来生产具有均质形态和无与伦比的机械性能的高密度TiC-Al 2 O 3复合材料。而且,所生产的复合材料可以成功地用于侵蚀性介质和摩擦学应用中。

更新日期:2021-04-01
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