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Enhanced photocatalytic water splitting with surface defective SrTiO 3 nanocrystals
Frontiers in Energy ( IF 3.1 ) Pub Date : 2021-04-08 , DOI: 10.1007/s11708-021-0735-2
Junying Liu , Zhidong Wei , Wenfeng Shangguan

Surface reconstructed SrTiO3 nanocrystals were synthesized by a thermal treatment process in presence of NaBH4 and SrTiO3 nanocrystals. The surface reconstruction of SrTiO3 nanocrystals is attributed to the introduction of surface oxygen vacancies or Ti sites (such as Ti3+ and Ti2+) during the hydrogenation treatment process. The light absorption and the charge transfer ability of SrTiO3 nanocrystals are simultaneously enhanced due to surface oxygen vacancies or Ti sites (such as Ti3+ and Ti2+), which are beneficial to photocatalytic water splitting. Meanwhile, these defects also change the redox potential of the photocatalysts. Since there existed a synergistic effect between the three, the ratio of hydrogen to oxygen production was also regulated.



中文翻译:

具有表面缺陷的SrTiO 3纳米晶体的增强光催化水分解

在NaBH 4和SrTiO 3纳米晶的存在下,通过热处理工艺合成了表面重建的SrTiO 3纳米晶。SrTiO 3纳米晶体的表面重建归因于在氢化处理过程中引入了表面氧空位或Ti位点(例如Ti 3+和Ti 2+)。光吸收和的SrTiO的电荷转移能力3纳米晶体被同时增强由于表面氧空位或Ti位点(如Ti 3+和Ti 2+),有利于光催化水分解。同时,这些缺陷也改变了光催化剂的氧化还原电势。由于三者之间存在协同作用,因此还调节了氢气与氧气的产生比例。

更新日期:2021-03-29
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