A white bulk sample of Li_2.10Sn_0.90O_2.85 was prepared by heating a compact pellet of a Li₂O and SnO₂ powder mixture with a molar ratio of 1.10:0.95 at 1000 °C for 6 h in Ar and consisted of colorless transparent crystal grains with sizes in the range of 20–80 μm. X-ray diffraction (XRD) reflections from a single crystal taken from the grains were indexed with C-centered monoclinic cell parameters (a = 5.29120(10) Å, b = 9.2033(2) Å, c = 10.0676(2) Å, β = 100.5030(10)°). The crystal structure was determined with the space group C2/c (No. 15) using Li₂SnO₃ as a starting model. The final structure refinement was performed by partial substitution of Li⁺ for Sn⁴⁺ and the introduction of O²⁻ defects with a formula of Li₂(Li_0.10Sn_0.90)O_2.85. Interstitial sites and continuous disordered distribution of Li⁺ ions were depicted in a differential Fourier synthesis map and an electron density distribution (EDD) map by the maximum entropy method (MEM). The disordered Li⁺ distribution was also revealed as broad peaks by ⁶Li magic-angle-spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy. The Li⁺ conductivity of Li_2.10Sn_0.90O_2.85 measured at 25 °C was 1.0 × 10⁻⁶ S·cm⁻¹, which was 10⁵ times greater than that of Li₂SnO₃.

通过在1000°C下在Ar中将摩尔比为1.10：0.95的Li ₂ O和SnO ₂粉末混合物的致密丸粒在Ar中加热6 h来制备Li _2.10 Sn _0.90 O _2.85的白色块状样品，该样品由无色透明组成。晶粒尺寸在20–80μm的范围内。来自晶粒的单晶的X射线衍射（XRD）反射采用以C为中心的单斜晶胞参数进行索引（a  = 5.29120（10）Å，b  = 9.2033（2）Å，c  = 10.0676（2）Å，β  = 100.5030（10）°）。用空间群C 2 / c确定晶体结构（No.15）使用Li ₂ SnO ₃作为起始模型。通过用Li ⁺部分取代Sn ⁴⁺并引入具有通式Li ₂（Li _0.10 Sn _0.90）O _2.85的O ^2-缺陷来进行最终的结构细化。Li ⁺离子的间隙位点和连续无序分布在微分傅里叶合成图和电子密度分布（EDD）图中通过最大熵方法（MEM）进行了描述。Li ⁺分布无序也显示为^6个宽峰李魔角自旋（MAS）核磁共振（NMR）光谱。在25℃下测得的Li _2.10 Sn _0.90 O _2.85的Li ⁺电导率为1.0×10 ^-6  S·cm ^-1，是Li ₂ SnO _3的10 ⁵倍。