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SSZ-13 supported Ir as an efficient catalyst for methylcyclopentane ring-opening reaction
Catalysis Communications ( IF 3.7 ) Pub Date : 2021-03-26 , DOI: 10.1016/j.catcom.2021.106311
Peng Shan , Panpan Niu , Huifang Zhang , Chuanhao Zhang , Ningyue Lu , Yan Wang , Binbin Fan , Ruifeng Li

Ir/H-SSZ-13 catalysts were used for methylcyclopentane (MCP) ring-opening (RO) reaction, and exhibit higher yields to RO products than H-ZSM-5, H-USY and Al2O3 supported Ir catalysts. Ir species supported on H-SSZ-13-A (about 200 nm) exhibits higher activity than those on H-SSZ-13-B (about 8 μm) due to its more accessible acid sites. Ir/H-SSZ-13-A gives higher reactivity than Ir/Al2O3, especially in the case of low Ir loading because of the promotion of the strong acid sites located on the external surface of H-SSZ-13-A. This work demonstrates that SSZ-13 supported metal is a potential catalyst for RO reaction.



中文翻译:

SSZ-13负载的Ir作为甲基环戊烷开环反应的有效催化剂

Ir / H-SSZ-13催化剂用于甲基环戊烷(MCP)开环(RO)反应,并且比H-ZSM-5,H-USY和Al 2 O 3负载的Ir催化剂对RO产物的产率更高。H-SSZ-13-A(约200 nm)上负载的Ir物种比H-SSZ-13-B(约8μm)上具有更高的酸性位点,因此具有更高的活性。Ir / H-SSZ-13-A具有比Ir / Al 2 O 3更高的反应性,特别是在低Ir负载的情况下,因为促进了H-SSZ-13-A外表面上的强酸位。这项工作表明SSZ-13负载金属是RO反应的潜在催化剂。

更新日期:2021-04-02
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