Novel low-firing BiMg₂PO₆ (BMP) and BiMg₂VO₆ (BMV) ceramics with excellent microwave properties were synthesized and analyzed. The Rietveld refinement indicated that BiMg₂MO₆ (M = P, V) ceramics crystallized in orthorhombic structure. The analysis results of the scanning electron microscope proved a dense and uniform microstructure. Further research showed that there was a strong correlation among permittivity, quality factor, and bulk density at different temperatures. The correlation between the properties and the structure of BiMg₂MO₆ (M = P, V) ceramics were characterized by the chemical bond theory. The outstanding dielectric properties of BiMg₂MO₆ (M = P, V) ceramics (BMP: ε_r = 12.503, Q × f = 25,760 GHz, τ_f = −20 × 10⁻⁶/°C; BMV: ε_r = 13.472, Q × f = 37,270 GHz, τ_f = −78 × 10⁻⁶/°C) make them expected to become the novel low temperature co-fired ceramics (LTCC).

合成并分析了具有优异微波性能的新型低烧 BiMg ₂ PO ₆ (BMP) 和 BiMg ₂ VO ₆ (BMV) 陶瓷。Rietveld 细化表明 BiMg ₂ MO ₆ (M = P, V) 陶瓷以正交结构结晶。扫描电子显微镜的分析结果证明了致密且均匀的微观结构。进一步的研究表明，不同温度下的介电常数、品质因数和体积密度之间存在很强的相关性。BiMg ₂ MO ₆性能与结构的相关性(M = P, V) 陶瓷的特点是化学键理论。BiMg ₂ MO ₆ (M = P, V) 陶瓷优异的介电性能(BMP: ε _r  = 12.503, Q  × f  = 25,760 GHz, τ _f  = −20 × 10 ^-6 /°C; BMV: ε _r  = 13.472, Q  × f  = 37,270 GHz, τ _f  = −78 × 10 ^-6 /°C) 使它们有望成为新型低温共烧陶瓷（LTCC）。