Abstract This review covers over fifty Pt (II) complexes of the compositions PtP3X (X = H, OL, NL, BL, Cl, SL, Br, or I). These complexes crystallized in three crystal classes: monoclinic (23 examples) triclinic (17 examples) and orthorhombic (11 examples). The PtP3Cl is most common with 23 examples. There are variable combinations of organophosphines monodentate – P; bidentate- P,P; P,N; P,B; and tridentate – P,P,P; P,O,P; P,N,P; and P,S,P. The structural parameters (Pt–L, L–Pt–L) are analyzed and discussed with an attention to the distortion of a square-planar geometry about the Pt (II) atoms as well as of trans-influence. The sums of Pt–L (x4) bond distances growing with covalent radius of the X-atoms.

中文翻译：

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PtP3X 衍生物中有机膦的可变组合：结构方面

摘要 本综述涵盖了 PtP3X（X = H、OL、NL、BL、Cl、SL、Br 或 I）组合物的五十多种 Pt (II) 配合物。这些配合物结晶为三类晶体：单斜晶（23 个实例）三斜晶（17 个实例）和斜方晶（11 个实例）。PtP3Cl 最常见，有 23 个例子。有机膦单齿 - P 有多种组合；双齿-P,P; P,N; P,B; 和三齿 - P,P,P; 流行音乐; P,N,P; 和 P，S，P。分析和讨论了结构参数（Pt-L，L-Pt-L），并关注关于 Pt（II）原子的方形平面几何形状的畸变以及反式影响。Pt-L (x4) 键距离的总和随着 X 原子的共价半径增长。