High Pressure Research ( IF 1.2 ) Pub Date : 2020-12-08 , DOI: 10.1080/08957959.2020.1853123 C. W. Wilson 1 , C. J. Ridley 2 , S. G. MacLeod 1 , C. L. Bull 2
ABSTRACT
The structural transformation of FePO from the trigonal berlinite phase to the orthorhombic CrVO phase has been studied using neutron diffraction at high pressure and high-temperature. The berlinite structure was compressed to a pressure of 5.2(2) GPa and amorphisation observed. Upon annealing at temperatures above 798(28) K the high pressure FePO structure was observed to form. This lowers the formation temperature required to promote this phase over the amorphous phase by ∼100 K compared to previous reports. No other structured phases were observed during the formation process which implies that the CrVO structure is the most stable form at high pressures and is kinetically inhibited from forming at low temperatures.
中文翻译:
FePO4-II的原位形成:中子衍射研究
摘要
FePO的结构转变 从三角硅钙石相到斜方晶CrVO已经在高压和高温下使用中子衍射研究了液相。将该berlinite结构压缩至5.2(2)GPa的压力并观察到非晶化。在高于798(28)K的温度下退火后,高压FePO观察到形成结构。与以前的报道相比,这将促进该相超过非晶相所需的形成温度降低了约100K。在形成过程中未观察到其他结构相,这表明CrVO 该结构是在高压下最稳定的形式,并且在动力学上抑制了在低温下形成。