In this study, we prepared Zn-MOFs as an ordinary, low-cost, and efficiency method taking advantage of zinc( ii ) acetate monohydrate and 1,3,5-benzenetricarboxylic acid in microwave-assisted ball milling. The Zn-MOFs were measured via scanning electron microscopy, infrared spectrometry, X-ray diffraction, and thermogravimetry. We explored its use as a photocatalyst for the degradation of tetracycline hydrochloride and Congo red from aqueous solutions. The results demonstrate that the kinetic model was appropriate for the removal of organic pollutants. In general, it is feasible, inexpensive, and effective to use metal organic framework (MOF) to treat waste liquid. Therefore, our findings indicate that Zn-MOFs have broad application vista in wastewater purification. Graphical abstract The Zn-MOFs were prepared as an ordinary, low-cost, and efficiency method taking advantage of zinc( ii ) acetate monohydrate and 1,3,5-benzenetricarboxylic acid in microwave-assisted ball milling. The Zn-MOFs were used as a photocatalyst for the degradation of tetracycline hydrochloride and Congo red from aqueous solutions. The results demonstrate that the kinetic model was appropriate for the removal of organic pollutants. In general, it is feasible, inexpensive, and effective to use metal organic framework (MOF) to treat waste liquid.

中文翻译：

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微波辅助球磨法去除废水中的四环素盐酸盐和刚果红制备Zn-MOFs

在这项研究中，我们利用微波辅助球磨中的乙酸锌（ii）一水合物和1,3,5-苯三甲酸，制备了一种常规，低成本且高效的Zn-MOFs。Zn-MOF通过扫描电子显微镜，红外光谱，X射线衍射和热重法测量。我们探索了其作为光催化剂从水溶液中降解盐酸四环素和刚果红的用途。结果表明，该动力学模型适用于去除有机污染物。通常，使用金属有机骨架（MOF）处理废液是可行，廉价且有效的。因此，我们的发现表明Zn-MOFs在废水净化中具有广泛的应用前景。图形摘要Zn-MOF是以普通的低成本制备的，乙酸锌（ii）一水合物和1,3,5-苯三甲酸在微波辅助球磨中的高效方法 Zn-MOF用作光催化剂，用于从水溶液中降解盐酸四环素和刚果红。结果表明，该动力学模型适用于去除有机污染物。通常，使用金属有机骨架（MOF）处理废液是可行，廉价且有效的。