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Observation of table-like magnetocaloric effect and large refrigerant capacity in Nd6Fe13Pd1–xCux compounds
Journal of Rare Earths ( IF 5.2 ) Pub Date : 2021-03-13 , DOI: 10.1016/j.jre.2021.03.009
Yusong Du 1, 2 , Chaohua Zhang 1 , Youming Lu 1, 2 , Junqin Li 1 , Gang Cheng 3 , Jiang Wang 3 , Guanghui Rao 3
Affiliation  

The table-like magnetocaloric effect is significant for the magnetic refrigeration applications above 20 K based on the Ericsson cycle. Herein, we prepared a series of Nd6Fe13Pd1–xCux (x = 0.05, 0.1, 0.15) compounds by the arc-melting method. These compounds show the single crystalline phase in the tetragonal Nd6Fe13Si-type structure with the space group I4/mcm. A magnetic phase transition from ferromagnetism to antiferromagnetism and a metamagnetic transition from the antiferromagnetic state to the ferromagnetic state are observed in each of the compounds. The compounds exhibit table-like magnetocaloric effects with large refrigerant capacities. A constant ΔSM in a temperature span of 40 K in the Nd6Fe13Pd0.85Cu0.15 compound are observed. For a field change of 0–5 T, the peak values of –ΔSM for the Nd6Fe13Pd0.95Cu0.05, Nd6Fe13Pd0.90Cu0.10, and Nd6Fe13Pd0.85Cu0.15 compounds are estimated to be 4.8, 4.6 and 4.4 J/(kg·K) with corresponding refrigerant capacity values of 323, 331 and 316 J/kg, respectively. The obtained table-like magnetocaloric effects with large refrigerant capacities as well as fairly small thermal and magnetic hysteresis deem these series of compounds good candidates for single-phase magnetic refrigeration based on the Ericsson cycle.



中文翻译:

Nd6Fe13Pd1–xCux 化合物中表状磁热效应和大制冷剂容量的观察

对于基于爱立信循环的 20 K 以上的磁制冷应用,表状磁热效应是显着的。在此,我们通过电弧熔化法制备了一系列 Nd 6 Fe 13 Pd 1– x Cu x ( x  = 0.05, 0.1, 0.15) 化合物。这些化合物显示出四方Nd 6 Fe 13 Si型结构的单晶相,空间群为I 4/ mcm. 在每种化合物中观察到从铁磁性到反铁磁性的磁性相变和从反铁磁性状态到铁磁性状态的超磁性转变。这些化合物表现出类似桌子的磁热效应,具有大的制冷剂容量。在Nd 6 Fe 13 Pd 0.85 Cu 0.15化合物中,在40 K的温度范围内观察到恒定的ΔSM 对于 0–5 T 的场变化, Nd 6 Fe 13 Pd 0.95 Cu 0.05、Nd 6 Fe 13 Pd 0.90的 -Δ S M峰值Cu 0.10和 Nd 6 Fe 13 Pd 0.85 Cu 0.15化合物估计为 4.8、4.6 和 4.4 J/(kg·K),相应的制冷剂容量值分别为 323、331 和 316 J/kg。获得的具有大制冷剂容量以及相当小的热磁滞和磁滞的表状磁热效应认为这一系列化合物是基于爱立信循环的单相磁制冷的良好候选者。

更新日期:2021-03-13
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