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Comparative characterization of iridium loading on catalyst assessment under different conditions
International Journal of Minerals, Metallurgy and Materials ( IF 5.6 ) Pub Date : 2021-03-13 , DOI: 10.1007/s12613-020-2058-4
Zahra Amirsardari , Akram Dourani , Mohamad Ali Amirifar , Nooredin Ghadiri Massoom

To discuss the potential role of iridium (Ir) nanoparticles loaded under atmospheric and high pressures, we prepared a series of catalysts with the same active phase but different contents of 10wt%, 20wt%, and 30wt% on gamma-alumina for decomposition of hydrazine. Under atmospheric pressure, the performance of the catalyst was better when 30wt% of the Ir nanoparticles was used with chelating agent that had greater selectivity of approximately 27%. The increase in the reaction rate from 175 to 220 h−1 at higher Ir loading (30wt%) was due to a good dispersion of high-number active phases rather than an agglomeration surface. As a satisfactory result of this investigation at high pressure, Ir catalysts with different weight percentages showed the same stability against crushing and activity with a characteristic velocity of approximately 1300 m/s.



中文翻译:

不同条件下催化剂评估中铱负载量的比较表征

为了讨论在大气压和高压下负载的铱(Ir)纳米颗粒的潜在作用,我们制备了一系列具有相同活性相但在γ-氧化铝上的含量分别为10wt%,20wt%和30wt%的催化剂,用于分解肼。在大气压下,当30wt%的Ir纳米粒子与螯合剂一起使用时,催化剂的性能更好,螯合剂的选择性更高,约为27%。反应速率从175增加到220 h -1较高的Ir负载量(30wt%)是由于大量活性相的良好分散而不是团聚表面引起的。作为在高压下进行的这项研究的令人满意的结果,具有不同重量百分比的Ir催化剂在约1300 m / s的特征速度下显示出相同的抗粉碎稳定性和活性。

更新日期:2021-03-15
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