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Gold-Catalyzed Formal [3+2]Cycloaddition of
Heterocycles ( IF 0.6 ) Pub Date : 2021-03-12 , DOI: 10.3987/com-20-s(k)71
Osamu Tamura , Nobuyoshi Morita , Kanae Ikeda , Hitomi Chiaki , Ryuto Araki , Kosaku Tanaka III , Yoshimitsu Hashimoto

Gold(III)-catalyzed formal [3+2] cycloaddition of p-quinones with 1-phenylpropenes in an ionic liquid, [EMIM][NTf2], enabled environmentally friendly, stereoselective synthesis of 2,3-dihydrobenzofuran neolignans in good yields. Moreover, the recycle of tThe gold catalyst in /ionic liquid was achievedcould be recycled at least five times, affording 2,3-dihydrobenzofuran in good yields.

中文翻译:

金催化的形式[3 + 2]环加成

在离子液体[EMIM] [NTf 2 ]中,金(III)催化对醌与1-苯基丙烯的正式[3 + 2]环加成反应,实现了环境友好,立体选择性地合成2,3-二氢苯并呋喃新木聚糖。而且,可以实现金催化剂在/离子液体中的再循环至少五次,从而以良好的收率得到2,3-二氢苯并呋喃。
更新日期:2021-05-19
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