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Simultaneous thermal analysis on the dynamical oxygen-lean combustion behaviors of coal in a O2/N2/CO2 atmosphere
Journal of the Energy Institute ( IF 5.6 ) Pub Date : 2021-03-10 , DOI: 10.1016/j.joei.2021.03.003
Hetao Su , Ning Kang , Bobo Shi , Huaijun Ji , Yunzhuo Li , Jingdong Shi

This study aims at study the dynamical oxygen-lean combustion behaviors of coal in a multi-gas concomitant atmosphere. Two coal samples from Bulianta and Yuwu collieries were collected for simultaneous thermal analysis in O2/N2 (21 vol%/79 vol%) and O2/N2/CO2 (15 vol%/80 vol%/5 vol%) atmospheres. Based on the TG-DTG curves, five evolution stages were analyzed. A delay phenomenon occurred for coal lean-oxygen combustion in O2/N2/CO2, which was obvious at IV stage with a high staged temperature and a wide temperature range. Furthermore, the kinetic parameters were obtained after determining the most probable mechanism function, showing an increased apparent activation energy at III stage and a decreased one at IV stage in O2/N2/CO2 compared with in O2/N2, which indicated that the low heat conduction coefficient of CO2 played a dominant role on these changes. The study also showed the relationship between the thermal formation rate and reaction rate constant.



中文翻译:

O 2 / N 2 / CO 2气氛中煤的动态贫氧燃烧行为的同时热分析

这项研究旨在研究煤在多种气体伴随气氛中的贫氧动态燃烧行为。收集了布里亚塔和玉雾煤矿的两个煤样,用于同时在O 2 / N 2(21 vol%/ 79 vol%)和O 2 / N 2 / CO 2(15 vol%/ 80 vol%/ 5 vol%)中进行热分析。)的气氛。基于TG-DTG曲线,分析了五个演化阶段。O 2 / N 2 / CO 2中贫煤氧气燃烧发生延迟现象,在IV阶段具有较高的阶段温度和较宽的温度范围,这一点很明显。此外,在确定最可能的机制功能后获得的动力学参数,示出了在III期增加的表观活化能和一个为O在IV级减少一个2 / N 2 / CO 2与为O相比2 / N 2,其表明CO 2的低导热系数在这些变化中起主要作用。研究还显示了热形成速率和反应速率常数之间的关系。

更新日期:2021-03-16
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