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A heteromesocrystal photocatalyst consisting of SnO2(head)-TiO2(tail) nanorod hybrids
Catalysis Communications ( IF 3.4 ) Pub Date : 2021-03-08 , DOI: 10.1016/j.catcom.2021.106301
Akita Atsunobu , Shoma Sugita , Shin-ichi Naya , Hiroaki Tada

Radial heteromesocrystals consisting of anisotropic SnO2(head)-TiO2(tail) nanorods with heteroepitaxial junction were synthesized by a hydrothermal reaction using SnO2 nanocrystals as the seeds. The heteromesocrystals exhibit photocatalytic activity for aerobic partial oxidation of ethanol to acetaldehyde much higher than radial TiO2 homomesocrystals. The striking photocatalytic activity of the former can stem from efficient light harvesting by multiple light scattering, effective charge separation by the one-directional electron transport through the TiO2 NR followed by the subsequent smooth interfacial electron transfer to SnO2, and electrocatalytic activity of SnO2 for two-electron oxygen reduction reaction.



中文翻译:

一种由SnO 2(头部)-TiO 2(尾部)纳米棒杂化物组成的杂介晶光催化剂

以SnO 2纳米晶为晶种,通过水热反应合成了由异质外延结的各向异性SnO 2(头部)-TiO 2(尾)纳米棒组成的径向异介晶。杂介晶对乙醇的好氧部分氧化为乙醛的光催化活性远高于放射状TiO 2均介晶。前者具有惊人的光催化活性,其源于通过多次光散射进行的有效光收集,通过TiO 2 NR的单向电子传输以及随后的顺畅界面电子转移至SnO 2以及对SnO的电催化活性进行的有效电荷分离。2个 用于两电子氧还原反应。

更新日期:2021-03-22
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