This review aims to highlight significant progress in the calculation of ⁷⁷Se NMR chemical shifts and spin – spin coupling constants involving selenium substantiated with a vast amount of experimental data. The material is arranged in two basic sections: the first one dealing with the calculation of ⁷⁷Se NMR chemical shifts and the second one dealing with the computation of spin – spin coupling constants involving ⁷⁷Se nucleus, namely ⁷⁷Se–¹H, ⁷⁷Se–¹³C and ⁷⁷Se–⁷⁷Se together with some more exotic types of couplings, ⁷⁷Se – ¹⁵N, ⁷⁷Se–¹⁹F, ⁷⁷Se–²⁹Si and ⁷⁷Se–³¹P. A special attention is focused on the stereoelectronic effects involving selenium atom and their manifestation in the ⁷⁷Se NMR spectra of organoselenium compounds studied with the aid of the modern calculation of ⁷⁷Se NMR parametres in combination with experimental results.

The bibliography includes 114 references.

这篇综述旨在突出在计算⁷⁷ Se NMR 化学位移和涉及硒的自旋-自旋耦合常数方面取得的重大进展，并得到了大量实验数据的证实。该材料分为两个基本部分：第一个部分处理⁷⁷ Se NMR 化学位移的计算，第二个部分处理涉及⁷⁷ Se 核的自旋-自旋耦合常数的计算，即⁷⁷ Se - ¹ H、⁷⁷ Se – ¹³ C 和⁷⁷ Se– ⁷⁷ Se 以及一些更奇特的联轴器类型，⁷⁷ Se – ¹⁵ N, ⁷⁷Se– ¹⁹ F、⁷⁷ Se– ²⁹ Si 和⁷⁷ Se– ³¹ P。特别关注涉及硒原子的立体电子效应及其在有机硒化合物的⁷⁷ Se NMR 光谱中的表现，借助现代计算⁷⁷ Se NMR 参数与实验结果相结合。

参考书目包括 114 篇参考文献。