Abstract

Stationary structures corresponding to non-stationary experiments with different initial conditions have been established for multistage reactions. Such structures are formed from various pairs of combinations of non-stationary reagent concentrations, and they remain constant over time in the course of reaction. They form lines of different curvature intersecting at one stationary point on the graphs of their concentration dependences for any reagent in one of the experiments. The stationary structures constructed in this way are specific for various reaction mechanisms; they supplement known relaxation characteristics and can be used to identify the mechanisms of chemical reactions based on the data of non-stationary experiments.

中文翻译：

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化学反应的平稳动力学结构

摘要

已经为多阶段反应建立了与具有不同初始条件的非平稳实验相对应的平稳结构。这样的结构由非固定试剂浓度的各种组合形成，并且它们在反应过程中随时间保持恒定。在其中一个实验中，它们在任何一种试剂的浓度依赖性图上的一个固定点处形成了不同曲率的线。以这种方式构造的固定结构对于各种反应机理是特定的。它们补充了已知的弛豫特性，可用于基于非平稳实验的数据来识别化学反应的机理。