Abstract

An approach, which was not previously described in the literature, has been developed for establishing new nonlinear kinetic conservation laws (NKCLs) in chemical reactions proceeding according to linear multistage mechanisms in isothermal gradientless reactors. These NKCLs are a mono-experimental variety of exact multireagent kinetic autonomous invariants that can be observed based on data measured in a single non-stationary experiment with certain specified initial conditions. This approach is applicable to the determination of the NKCLs of specific reactions occurring in closed and open gradientless reactors.

中文翻译：

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线性化学反应中的非线性动力学守恒律

摘要

已经开发了一种在文献中未曾描述过的方法，该方法用于在等温无梯度反应器中根据线性多级机理在化学反应中建立新的非线性动力学守恒定律（NKCL）。这些NKCL是精确的多试剂动力学自主变量的单实验种类，可以基于在某些特定初始条件下的单个非平稳实验中测得的数据进行观察。该方法适用于确定在封闭式和开放式无梯度反应器中发生的特定反应的NKCL。