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Mechanism of novel MoS 2 -modified biochar composites for removal of cadmium (II) from aqueous solutions
Environmental Science and Pollution Research Pub Date : 2021-03-04 , DOI: 10.1007/s11356-021-13199-9
Zulqarnain Haider Khan 1, 2, 3 , Minling Gao 1 , Weiwen Qiu 4 , Zhengguo Song 1
Affiliation  

The purpose of this study was to develop a MoS2-impregnated biochar (MoS2@BC) via hydrothermal reaction for adsorption of cadmium (Cd) from an aqueous solution. The prepared adsorbents were characterized, and their abilities to remove Cd(II) were evaluated. The Langmuir and pseudo-second-order models better described the removal of Cd(II) by MoS2@BC. The prepared MoS2@BC exhibited excellent monolayer adsorption capacity. The S-containing functional groups on MoS2@BC enhanced the adsorption of Cd(II). Multiple Cd(II) sorption mechanisms were identified; including Cd(II)-π interactions, ion exchange, electrostatic interaction, and complexation. The dominant mechanism involved Cd-O (38.3%) bonds and Cd-S complexation (61.7%) on MoS2@BC. The as-prepared MoS2@BC is both economical and efficient, making it an excellent material for environmental Cd(II) remediation.



中文翻译:

新型MoS 2改性生物炭复合材料从水溶液中去除镉(II)的机理

这项研究的目的是通过水热反应开发一种MoS 2浸渍生物炭(MoS 2 @BC),用于从水溶液中吸附镉(Cd)。对制备的吸附剂进行表征,并评估其去除Cd(II)的能力。Langmuir模型和伪二阶模型更好地描述了MoS 2 @BC对Cd(II)的去除。制备的MoS 2 @BC表现出优异的单层吸附能力。MoS 2上的含S官能团@BC增强了Cd(II)的吸附。确定了多种Cd(II)吸附机理;包括Cd(II)-π相互作用,离子交换,静电相互作用和络合。占主导地位的机制涉及MoS 2 @BC上的Cd-O(38.3%)键和Cd-S络合(61.7%)。所制备的MoS 2 @BC既经济又高效,使其成为用于环境Cd(II)修复的极佳材料。

更新日期:2021-03-04
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