Complexes of the general formula Cp₂Ti(IV)L, Cp₂Zr(IV)L, Cp₂Ti(IV)L¹ and Cp₂Zr(IV)L¹ have been synthesized with N,N’-bis(2-pyridyl)pyridine-2,6-dicarboxamide (H₂L) and 9,10-phenanthrenequinone dioxime (H₂L¹). The complexes have been characterized by different spectral techniques and their reduction reactions have been carried out with hydrated electron as reducing radical, mechanism which has been explored pulse radiolytically. Theoretical calculations have been performed to understand the effect of chelation and electron transfer processes in complexes.

中文翻译：

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酰胺和肟官能团新合成的Ti（IV）/ Zr（IV）配合物的电子转移研究：脉冲辐解和理论启示

合成了具有N，N'-bis（2 ）的通式Cp ₂ Ti（IV）L，Cp ₂ Zr（IV）L，Cp ₂ Ti（IV）L ¹和Cp ₂ Zr（IV）L ^1的配合物-吡啶基）吡啶-2,6-二甲酰胺（H ₂ L）和9,10-菲醌二肟（H ₂ L ¹）。配合物已通过不同的光谱技术进行了表征，其还原反应是利用水合电子作为还原基团进行的，这种机理已通过脉冲辐射的方法进行了探索。已经进行了理论计算以了解络合物中螯合和电子转移过程的影响。