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Chemical analysis of corn cob-based biochar and its role as water decontaminants
Journal of Taibah University for Science ( IF 2.8 ) Pub Date : 2021-03-03 , DOI: 10.1080/16583655.2021.1876350
Eman A. Assirey 1 , Lenah R. Altamimi 1
Affiliation  

Production of biochar is accomplished by pyrolysis of corncobs at 350 °C (BC-350) and 450 °C (BC-450) under oxygen-limited conditions. The chemical and physical properties were investigated via XRD, FTIR, BET, SEM and EDX analysis. Batch experiments were conducted for the adsorption of Pb2+ ions from aqueous solution onto biochar with regards to pH, contact time, biochar dose and initial Pb2+ concentration. The adsorption efficiency of Pb2+ was increased as increasing pH and biochar dose up to 1.5 g/L. Kinetic and isothermal studies demonstrated that the experimental data were fitted with the pseudo-second-order model, Langmuir and Freundlich isotherms. The study emphasized the preferable pyrolysis temperature which is 450 °C. According to the Dubinin-Kaganer-Radushkevich (DKR) model, the adsorption process of Pb2+ was a chemical and endothermic reaction. Results showed the applicability of corncob based biochar to be used as an efficient and low cost adsorbent for Pb2+ ions removal.



中文翻译:

玉米芯生物炭的化学分析及其作为去污剂的作用

生物炭的生产是通过在氧气受限的条件下,将玉米芯在350°C(BC-350)和450°C(BC-450)上热解来完成的。通过XRD,FTIR,BET,SEM和EDX分析研究了化学和物理性质。关于pH,接触时间,生物炭剂量和初始Pb 2+浓度,进行了分批实验以从水溶液中吸附Pb 2+离子到生物炭上。Pb 2+的吸附效率随着pH和生物炭剂量增加至1.5 g / L而增加。动力学和等温研究表明,实验数据符合拟二阶模型,Langmuir和Freundlich等温线。研究强调了优选的热解温度为450°C。根据Dubinin-Kaganer-Radushkevich(DKR)模型,Pb 2+的吸附过程是化学反应和吸热反应。结果表明,基于玉米芯的生物炭可用作去除Pb 2+离子的高效低成本吸附剂。

更新日期:2021-03-03
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