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Low temperature carrier transport mechanism and photo-conductivity of WSe2
Journal of Alloys and Compounds ( IF 5.8 ) Pub Date : 2021-03-02 , DOI: 10.1016/j.jallcom.2021.159369
Manjot Kaur , Kulwinder Singh , Ishant Chauhan , Hardilraj Singh , Ram K. Sharma , Ankush Vij , Anup Thakur , Akshay Kumar

This work reports the electrical-transport and temperature-dependent photoconductivity in tungsten diselenide (WSe2) thin films. Temperature-dependent electrical conductivity has been demonstrated using different models. At lower temperatures (< 190 K), carriers become localized to small regions in the film due to Mott’s hopping mechanism. The middle-temperature region (190–273 K) follows Seto’s parameters and obtained low barrier height (0.0873 eV) may be responsible for the improved carrier mobility. At higher temperature (> 273 K) region, thermally activated conduction is dominated with two activation energies of ~138 meV and 98 meV. The peaks obtained in photoluminescent analysis attributes to the presence of mid-bandgap states or defect states which play an important role in the photoconductivity of WSe2. The transient photoconductivity measurements show consistent temperature-dependent behaviour. The effect of light intensity and wavelength variation on the photoconductivity of WSe2 thin films is also discussed. The photo-current is 1.19 * 10−5 A at 125 K, while at 350 K was observed to be 3.12 * 10−4 A. The light-on/off current cycles show that the current can recover to its initial state after various cycles, which points to the WSe2 thin-film device's stable and reversible properties that can be used in optoelectronic applications.



中文翻译:

WSe 2的低温载流子传输机理和光电导性

这项工作报告了二硒化钨(WSe 2)薄膜中的电传输和温度相关的光电导性。已经使用不同的模型证明了温度相关的电导率。在较低的温度(<190 K)下,由于莫特的跳跃机制,载流子变得局限于薄膜中的小区域。中间温度区域(190–273 K)遵循Seto的参数,并且获得的低势垒高度(0.0873 eV)可能是改善载流子迁移率的原因。在较高温度(> 273 K)区域,热激活的传导主要由〜138 meV和98 meV的两个激活能量决定。在光致发光分析中获得的峰归因于中带隙态或缺陷态的存在,它们在WSe的光电导中起重要作用2。瞬态光电导率测量显示出一致的温度依赖性行为。还讨论了光强度和波长变化对WSe 2薄膜光电导性的影响。在125 K时,光电流为1.19 * 10 -5 A,而在350 K时,光电流为3.12 * 10 -4A。开/关电流周期表明,经过各种变化,电流可以恢复到其初始状态。周期,这表明WSe 2薄膜器件具有稳定且可逆的特性,可用于光电应用。

更新日期:2021-03-07
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