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The Co–Ni–Zr Phase Diagram in the Zr–ZrCo–ZrNi Region I. Phase Equilibria in the Zr–ZrCo–ZrNi System at Subsolidus Temperature, 900°C, and 800°C
Powder Metallurgy and Metal Ceramics ( IF 0.9 ) Pub Date : 2021-03-02 , DOI: 10.1007/s11106-021-00186-5
O.L. Semenova , V.M. Petyukh , O.S. Fomichov

The phase equilibria in the Zr–ZrCo–ZrNi system at subsolidus temperature and at 900 and 800°C were first studied using physicochemical analysis methods, and solidus surfaces and isothermal sections at 900 and 800°C were constructed. Isomorphic Zr2Co and Zr2Ni compounds with a tetragonal crystal structure of AlCu2 (θ) type form a continuous series of solid solutions dividing the Zr–ZrCo–ZrNi system into two subsystems: Zr–Zr2Co–Zr2Ni and ZrCo–ZrNi–Zr2Ni–Zr2Co. The equilibria on the solidus surface of the Zr–Zr2Co–ZrCo–Zr2Ni system and at 900°C differ significantly. This is associated with the Zr3Co-based η phase formed by peritectoid reaction 〈β − Zr〉 + 〈Zr2Co〉 → η at 980°C, being close to theL ↔ θ + β eutectic crystallization temperature (986°C), in the binary Zr–Co system. At 900 and 800°C, the 𝜂 phase dissolves up to 14.5% Ni. The solidus surface of the ternary Zr2Co–Zr2Ni–ZrCo–ZrNi system shows a three-phase equilibrium of the θ phase with the ZrCo (δ) and ZrNi (δ2) phases of the ZrCo–ZrNi quasibinary section: δ + δ2 + θ. The plane of this tie-line triangle extends significantly at 900 and 800°C as the solubility of nickel in the cubic ZrCo-based phase of CsCl type changes. At room temperature, all alloys of the ZrCo–ZrNi–Zr2Ni–Zr2Co subsystem should contain three phases: δ + δ2 + θ. The solidus surface of the Zr–ZrCo ZrNi system is thus completed by surfaces corresponding to the homogeneity regions of the δ, δ2, δ, and β phases, θ + δ + δ2 tie-line triangle plane, and ruled surfaces representing the upper boundary of the two-phase θ + δ2, θ + δ, and θ + δ volumes. At 900 and 800°C, two three-phase equilibria, η + θ + β and δ + δ2 + θ, are observed in the system.



中文翻译:

Zr–ZrCo–ZrNi区中的Co–Ni–Zr相图I.亚固相线温度,900°C和800°C下Zr–ZrCo–ZrNi系统中的相平衡

首先使用理化分析方法研究了亚固相线温度以及900和800°C下Zr–ZrCo–ZrNi系统的相平衡,并构造了900和800°C的固相表面和等温截面。具有AlCu2(θ)型四方晶体结构的同构Zr 2 Co和Zr 2 Ni化合物形成一系列连续的固溶体,将Zr–ZrCo–ZrNi系统分为两个子系统:Zr–Zr 2 Co–Zr 2 Ni和ZrCo -ZrNi锆2的Ni-Zr的2有限公司的Zr的Zr的固相线表面上的平衡2共同ZrCo -锆2 Ni体系,并在900℃下显著不同。这与Zr 3相关通过包析反应形成的Co基η相< β  - > + < Zr的2 CO >→交通 η在980℃,是接近大号 ↔  θ  +  β共晶结晶温度(986℃),在二进制的Zr合作系统。在900和800°C下,the相最多可溶解14.5%的Ni。的三元的Zr固相线表面2共同的Zr 2 Ni基ZrCo-ZrNi系统显示与ZrCo(δ)和ZrNi(δ的θ相的三相平衡2)的ZrCo-ZrNi quasibinary部的阶段:δ +δ 2+θ。随着镍在CsCl型立方ZrCo基相中的溶解度变化,该联系线三角形的平面在900和800°C时明显延伸。在室温下,将ZrCo-ZrNi -锆的所有合金2的Ni-Zr的2钴子系统应包含三个阶段:δ+δ 2 +θ。所述Zr的ZrCo ZrNi系统的固相线表面因此通过对应于δ的均匀区域的表面完成的,δ 2,δ,β相,θ+δ+δ 2联络线三角形平面,并且排除代表的表面两相θ+δ的上边界2,θ+δ,θ+δ的卷。在900和800℃时,两个三相平衡,η+θ+β和δ+δ 2 +θ,在该系统中观察到。

更新日期:2021-03-02
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