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Synthesis of porous Cu2FeSnS4 particles via solvothermal process for removal of organic acid fuchsin dye pollutant from wastewater
Nano-Structures & Nano-Objects Pub Date : 2021-02-25 , DOI: 10.1016/j.nanoso.2021.100697
Nagaraju Mukurala , Krishnaiah Mokurala , Siddhartha Suman , Ajay K. Kushwaha

Herein, solvothermal synthesized Cu2FeSnS4 (CFTS) particles are reported as an efficient adsorbent for removing acid fuchsin (AF) dye pollutants from the wastewater. Variation in synthesis reaction time led to have a porous sphere, sheet-flakes, and intermixed flower-sheet morphologies of CFTS particles synthesized at 200 °C for 6 h, 12 h and 18 h, respectively. The effect of surface morphologies of the CFTS particles on dye adsorption capability is examined. The porous spheres of CFTS particles have shown approximately (89.25 ± 2.21)% of AF dye adsorption within 10 min, and the value reaches (97.12 ± 0.76)% in 60 min. The high adsorption capacity i.e (123.12 ± 2.09) mg/g is obtained for porous spherical CFTS particles. The adsorption isotherm and kinetic studies reveal that the dye adsorption can be explained by the Langmuir isotherm and pseudo-second-order kinetic model. Further, the porous CFTS particles exhibit good stability and reusability of the adsorbent for wastewater purification. The present study results indicate that porous earth-abundant and non-toxic quaternary chalcogenide particles can be low cost, highly efficient adsorbent for removing organic acid fuchsin (AF) dye pollutants from wastewater.



中文翻译:

多孔Cu 2 FeSnS的合成4 溶剂热法去除废水中的有机酸品红染料污染物

溶剂热合成Cu 2 FeSnS4据报道(CFTS)颗粒是从废水中去除酸性品红(AF)染料污染物的有效吸附剂。合成反应时间的变化导致CFTS颗粒分别在200°C,6 h,12 h和18 h时具有多孔球体,片状薄片和混合的花片形态。考察了CFTS颗粒的表面形态对染料吸附能力的影响。CFTS颗粒的多孔球在10分钟内显示出约(89.25±2.21)%的AF染料吸附,在60分钟内该值达到(97.12±0.76)%。对于多孔球形CFTS颗粒,获得了高吸附容量,即(123.12±2.09)mg / g。吸附等温线和动力学研究表明,染料吸附可以用Langmuir等温线和拟二级动力学模型来解释。进一步,多孔CFTS颗粒具有良好的稳定性和吸附剂用于废水净化的可重复使用性。目前的研究结果表明,多孔的富含地球和无毒的季铵硫属元素颗粒可以是低成本,高效的吸附剂,用于去除废水中的有机酸品红(AF)染料污染物。

更新日期:2021-02-26
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