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Excellent organic dye adsorption capacity and recyclability of hydrothermally synthesized α-Fe2O3 nanoplates and nanorices
Journal of Science: Advanced Materials and Devices ( IF 7.382 ) Pub Date : 2021-02-25 , DOI: 10.1016/j.jsamd.2021.02.006
Pham Kim Ngoc , Trung Kien Mac , Huu Tuan Nguyen , Do Thanh Viet , Tran Dang Thanh , Pham Van Vinh , Bach Thang Phan , Anh Tuan Duong , Raja Das

α-Fe2O3 and Fe3O4 nanoplates and nanorices were synthesized by hydrothermal reaction and used for organic pollutant adsorption and removal studies. The effect of size and morphology of α-Fe2O3 and Fe3O4 nanoplates and nanorices on the dye adsorption efficiency were investigated systematically. The adsorption studies showed a good selectivity and high adsorption capacity (~93%) of the α-Fe2O3 nanoplates towards congo red (C.R.) dye, due to the formation of hydrogen bonding between amine group (─ NH2) of C.R. and surface carboxylate group (─ COOH), and adsorbed ─ OH groups of α-Fe2O3 nanoplates. The α-Fe2O3 nanoplates also showed excellent recyclability with negligible loss of the adsorption capacity, owing to their stable morphology and crystal structure. The excellent C.R. adsorption capacity of the α-Fe2O3 nanoplates was further confirmed by conducting experiments with a solution containing a mixture of dyes. Our findings indicate that the synthesized α-Fe2O3 nanoplates have a great potential in removing industrial waste, such as C.R. from polluted water.



中文翻译:

水热合成的α -Fe 2 O 3纳米板和纳米粒子具有优异的有机染料吸附能力和可回收性

的α-Fe 2 ö 3和Fe 3个ö 4纳米片和nanorices采用水热反应合成的,并用于有机污染物吸附除去的研究。系统研究了α -Fe 2 O 3和Fe 3 O 4纳米板的大小和形态以及纳米颗粒对染料吸附效率的影响。吸附研究表明,由于胺基(─NH 2)之间形成氢键,α -Fe 2 O 3纳米板对刚果红(CR)染料具有良好的选择性和高吸附能力(〜93%)。)和表面羧酸盐基团(─COOH))和吸附的α -Fe 2 O 3纳米板的─OH基团。由于其稳定的形态和晶体结构,α -Fe 2 O 3纳米板还显示出优异的可回收性,而吸附能力的损失可忽略不计。通过使用含有染料混合物的溶液进行实验,进一步证实了α -Fe 2 O 3纳米板的出色的CR吸附能力。我们的发现表明合成的α -Fe 2 O 3 纳米板在去除工业废水(如污水中的CR)方面具有巨大潜力。

更新日期:2021-02-25
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