Crystallography Reports ( IF 0.6 ) Pub Date : 2021-02-25 , DOI: 10.1134/s106377452101020x A. A. Zolotarev , S. V. Krivovichev , M. S. Avdontceva , E. S. Zhitova , N. V. Shchipalkina , I. V. Pekov
Abstract
Single crystals of “malakhovite” (an anthropogenic silico-oxide from burnt dumps of the Chelyabinsk coal basin; sp. gr. P\(\bar {1}\), a = 10.555(4) Å, b = 10.928(3) Å, c = 9.059(3) Å, α = 106.338(12)°, β = 95.87(7)°, γ = 124.40(2)°, V = 781.0(5) Å3, Z = 1, R1 = 0.0378 have been investigated by electron-probe microanalysis, Raman spectroscopy, and X-ray diffraction analysis. The idealized formula of the mineral is Ca4(Fe\(_{{8.56}}^{{3 + }}\)Mg1.72Ca0.82Fe\(_{{0.55}}^{{2 + }}\)Mn0.22Ti0.13)Σ12.00(Fe\(_{{6.48}}^{{3 + }}\)Al2.82Si2.71)Σ12.01O40. It is shown that malakhovite is not only chemical but also crystal chemical anthropogenic analogue of khesinite (Ca4Mg2Fe\(_{{10}}^{{3 + }}\)O4Fe\(_{{10}}^{{3 + }}\)Si2O36). The relationships between the malakhovite and the minerals from the dorrite–khesinite series of the rhönite group in the sapphirine supergroup are discussed.
中文翻译:
车里雅宾斯克煤盆地(南乌拉尔)的人为焚烧垃圾场中的钾钠锰矿的人为类似物“ Malakhovite”的晶体化学
摘要
“malakhovite”(一个人为从里雅宾斯克煤盆地的烧焦转储硅-氧化物的单晶; SP克。。P \(\巴{1} \) ,一个= 10.555(4),b = 10.928(3)埃,ç = 9.059(3)埃,α= 106.338(12)°,β= 95.87(7)°,γ= 124.40(2)°,V = 781.0(5)3,ž = 1,- [R 1 =通过电子探针显微分析,拉曼光谱和X射线衍射分析研究了0.0378,该矿物的理想配方为Ca 4(Fe \(_ {{{8.56}} ^ {{3 +}} \) Mg 1.72 Ca 0.82 Fe \(_ {{0.55}} ^ {{{2 +}} \)的Mn 0.22的Ti 0.13)Σ12.00(FE \(_ {{6.48}} ^ {{3 +}} \)的Al 2.82的Si 2.71)Σ12.01 Ö 40。结果表明,孔雀石不仅是化学的,而且是晶体化学的人为类似的钾钠锰矿(Ca 4 Mg 2 Fe \(_ {{10}} ^ {{3 +}} \) O 4 Fe \(_ {{10} } ^ {{{3 +}} \) Si 2 O 36)。讨论了蓝宝石超群中菱锰矿中菱锰矿-水钠锰矿系列中的矿物与孔雀石矿物之间的关系。