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Effect of melt-spinning speed on the microstructure and magnetic properties of Al–Cu–Fe alloy-doped SmCo 5 ribbons
Applied Physics A ( IF 2.5 ) Pub Date : 2021-02-25 , DOI: 10.1007/s00339-021-04359-2
Li-Zhu Wang , Shu Wang , Zhi-Ying Zhang , Hong-Wei Wang , Ji-Bing Sun , Chun-Xiang Cui

Multielement alloy doping is the feature of this paper, and disclosing the relationship between non-equilibrium microstructure and magnetic properties after rapid cooling is the key point. 3 wt% eutectic Al82.8Cu17Fe0.2 alloy was doped into SmCo5 alloy, followed by melt-spinning at 10–40 m/s. It is found all ribbons are composed of Sm(Co, M)5 and Sm2(Co, M)7 phases, but non-equilibrium solidification at different cooling rates results in different distribution characteristics of phases and magnetic properties of the ribbons. The 10 m/s ribbons are composed of Sm–Cu- and Co-rich Sm(Co, M)5 phases and then the lamellate Sm2(Co, M)7 coexists with CeCo5-type Sm(Co, M)5 grains in the 25 m/s ribbons, while the 40 m/s ribbons form a cellular microstructure with Sm2(Co, M)7 grain boundaries and Sm(Co, M)5 intracellular grains. Correspondingly, the coercivity, remanence, and maximum magnetization of 40 m/s ribbons are 74.3%, 64.3%, and 53.2% higher than those of 10 m/s ribbons. At the same time, the coercivity mechanism and microstructure evolution are discussed.



中文翻译:

熔体纺丝速度对掺Al-Cu-Fe合金的SmCo 5薄带组织和磁性能的影响

多元素合金掺杂是本文的特点,揭示快速冷却后非平衡组织与磁性能之间的关系是关键。将3 wt%的低共熔Al 82.8 Cu 17 Fe 0.2合金掺杂到SmCo 5合金中,然后以10-40 m / s的速度进行熔融纺丝。发现所有带均由Sm(Co,M)5和Sm 2(Co,M)7相组成,但是在不同冷却速率下的非平衡凝固导致带的相分布和磁性能不同。10 m / s的碳带由富Sm-Cu和富Co的Sm(Co,M)5相组成,然后是薄片状Sm。在25 m / s的色带中2(Co,M)7与CeCo 5型Sm(Co,M)5颗粒共存,而40 m / s的色带与Sm 2(Co,M)7的晶粒形成细胞微结构。边界和Sm(Co,M)5个胞内颗粒。相应地,40 m / s碳带的矫顽力,剩磁和最大磁化强度分别比10 m / s碳带高74.3%,64.3%和53.2%。同时讨论了矫顽力机理和微观组织演变。

更新日期:2021-02-25
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