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The Effect of Graphite and Fe2O3 Addition on Hydrolysis Kinetics of Mg-Based Hydrogen Storage Materials
International Journal of Photoenergy ( IF 3.2 ) Pub Date : 2021-02-24 , DOI: 10.1155/2021/6651541
Kun Yang 1 , Hongyun Qin 1 , Junnan Lv 1 , Rujun Yu 1 , Xia Chen 1 , Zengdian Zhao 1 , Yongjie Li 1 , Fang Zhang 2 , Xianchang Xia 2 , Qiang Fu 1 , Ming Wang 1
Affiliation  

In this paper, graphite and Fe2O3 are introduced into MgH2 powder by the method of hydrogenation after magnetic grinding. Hydrogen storage materials which composite of MgH2–5 wt.% C and MgH2–5 wt.% C–5 wt.% Fe2O3 are successfully prepared. The physical structure of these materials was analyzed and characterized by XRD, SEM, etc. Furthermore, the influence of graphite and Fe2O3 on the hydrolysis of MgH2 was systematically investigated. The results show that MgH2–C–Fe2O3 composite powder has the fastest hydrogen release rate in municipal drinking water and the highest conversion rate. Graphite and Fe2O3 can effectively reduce the activation energy of the hydrolysis reaction of MgH2 and improve the hydrolysis kinetics of MgH2. The synergistic effect of the coaddition of graphite and Fe2O3 can significantly increase the hydrolysis conversion rate of MgH2 and improve the hydrolysis kinetics.

中文翻译:

石墨和Fe2O3添加对镁基储氢材料水解动力学的影响

本文通过磁力研磨后的氢化方法,将石墨和Fe 2 O 3引入MgH 2粉末中。成功制备了由MgH 2 -5 wt。%C和MgH 2 -5 wt。%C-5 wt。%Fe 2 O 3组成的储氢材料。通过XRD,SEM等对这些材料的物理结构进行了分析和表征。此外,系统地研究了石墨和Fe 2 O 3对MgH 2水解的影响。结果表明,MgH 2 -C-Fe 2 O 3复合粉在城市饮用水中的氢释放速率最快,转化率最高。石墨和Fe 2 ö 3可以有效地减少的MgH的水解反应的活化能2和改善的MgH的水解动力学2。石墨和Fe 2 O 3的共添加的协同作用可以显着提高MgH 2的水解转化率并改善水解动力学。
更新日期:2021-02-24
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