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Synthesis of Polycyclic Chromene Cores through Gold (I)‐Catalyzed Intramolecular Hydroarylation Reaction (IMHA)
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-02-24 , DOI: 10.1002/ejoc.202100092 Antonia Iazzetti 1 , Antonio Arcadi 2 , Giancarlo Fabrizi 3 , Andrea Fochetti 4 , Roberta Franzini 5 , Francesca Ghirga 6 , Antonella Goggiamani 4 , Federico Marrone 3 , Andrea Serraiocco 3
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-02-24 , DOI: 10.1002/ejoc.202100092 Antonia Iazzetti 1 , Antonio Arcadi 2 , Giancarlo Fabrizi 3 , Andrea Fochetti 4 , Roberta Franzini 5 , Francesca Ghirga 6 , Antonella Goggiamani 4 , Federico Marrone 3 , Andrea Serraiocco 3
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A gold (I)‐catalyzed approach for the construction of polycyclic chromene cores was developed. The reaction proceeds in good to excellent yields under mild condition. In the presence of unsymmetrically substituted propargylic ethers a good selectivity has been achieved.
中文翻译：
通过金（I）催化的分子内氢化反应（IMHA）合成多环烯核
开发了一种金（I）催化的多环苯并噻吩核的构建方法。在温和的条件下，反应以良好的收率进行。在不对称取代的炔丙基醚的存在下，已经实现了良好的选择性。
更新日期：2021-03-15
中文翻译：
通过金（I）催化的分子内氢化反应（IMHA）合成多环烯核
开发了一种金（I）催化的多环苯并噻吩核的构建方法。在温和的条件下，反应以良好的收率进行。在不对称取代的炔丙基醚的存在下，已经实现了良好的选择性。
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