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Photoluminescence properties of Er3+ and Eu3+ ions based on oxide host for optical temperature sensing with high sensitivity
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy ( IF 4.4 ) Pub Date : 2021-02-24 , DOI: 10.1016/j.saa.2021.119602
Jiajun Chen , Fangsheng Qian , Chen Zhuang , Yining Zhang , Jia Zhang

Motivated from increasing demands of non-contact optical temperature sensing, the Yb3+-Er3+ and Eu3+ doped NaY9Si6O26 (NYS) oxide phosphors were designed by high-temperature solid-state reaction method. The phase purity of the as-prepared samples was checked from XRD patterns. For the upconversion luminescence in NYS:Yb3+,Er3+, the optimal Er3+ doping content was determined to be 1 mol%, and the characteristic emission peaks of Er3+ were observed in the region of 500–700 nm. In Eu3+ activated NYS phosphors, it has been found that the emissions originating in 5D1 and 5D0 levels demonstrate different change tendencies in intensity with Eu3+ doping concentration. By studying the temperature-dependent luminescent spectra, it was indicated that the emissions intensities from different excited states of Er3+ change differently with temperature. Two kinds of fluorescence intensity ratio (FIR) strategies were used in NYS:10%Yb3+,1%Er3+, containing thermally-coupled levels and non-thermally-coupled levels. In the NYS:3%Eu3+ phosphor, it was found that the FIR for 577 and 536 nm emissions follows a linear relation with temperature. The high sensitivities in the present phosphors indicate the potential application in optical temperature sensing.



中文翻译:

基于氧化物主体的Er 3+和Eu 3+离子的光致发光特性,可实现高灵敏度的光学温度传感

出于对非接触式光学温度传感的日益增长的需求,通过高温固态反应方法设计了Yb 3+ -Er 3+和Eu 3+掺杂的NaY 9 Si 6 O 26(NYS)氧化物荧光粉。从XRD图检查所制备样品的相纯度。对于NYS:Yb 3+,Er 3+中的上转换发光,确定最佳Er 3+掺杂含量为1 mol%,并且在500-700 nm区域观察到Er 3+的特征发射峰。在Eu 3+活化的NYS磷光体,已发现源自5 D 15 D 0的发射具有随Eu 3+掺杂浓度而变化的强度变化趋势。通过研究随温度变化的发光光谱,表明Er 3+不同激发态的发射强度随温度变化。NYS中使用了两种荧光强度比(FIR)策略:10%Yb 3+,1%Er 3+,包括热耦合能级和非热耦合能级。在纽约州:3%Eu 3+磷光体,发现577和536 nm发射的FIR随温度呈线性关系。本发明的磷光体中的高灵敏度表明在光学温度感测中的潜在应用。

更新日期:2021-03-02
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