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Electrochemical mitigation of hydrogen sulfide in deep-pit swine manure storage
Science of the Total Environment ( IF 8.2 ) Pub Date : 2021-02-24 , DOI: 10.1016/j.scitotenv.2021.146048
Lingkan Ding , Hongjian Lin , Brian Hetchler , Yuchuan Wang , Wei Wei , Bo Hu

Hydrogen sulfide (H2S) is a toxic and hazardous gas and is commonly present in livestock operations, which occasionally causes associated exposure accidents. This study evaluated the effectiveness of electrochemical control of H2S in lab-scale swine manure storage using different electrode materials, and further selected suitable materials to demonstrate the performance of a pilot-scale field test in the deep-pit manure storage of a 200-head swine barn. In the lab-scale test, electrochemical sulfide oxidation mainly contributed to the H2S mitigation, resulting in high H2S removal efficiencies when using low carbon steel (LCS) and stainless steel 304 (SS304) as electrodes. Based on their better H2S treatment performance and lower material costs, LCS and SS304 were selected for the pilot-scale test. In a 92-day operation, the pilot-scale demonstration showed H2S removal efficiencies of 84.0% and 63.5% for LCS and SS304, respectively. A techno-economic assessment indicated that the installation and operation of the electrochemical system accounted for 16% of barn construction cost using LCS as electrodes. Further optimization may substantially decrease the electrode material consumption and the overall cost.



中文翻译:

电化学还原深坑猪粪中的硫化氢

硫化氢(H 2 S)是一种有毒有害气体,通常存在于畜牧业中,偶尔会引起相关的暴露事故。这项研究评估了使用不同的电极材料对实验室规模的猪粪中H 2 S进行电化学控制的有效性,并进一步选择了合适的材料来证明200磅深坑粪便中试规模现场测试的性能。头猪舍。在实验室规模的测试中,使用低碳钢(LCS)和不锈钢304(SS304)作为电极时,电化学硫化物的氧化主要有助于缓解H 2 S,从而提高了H 2 S的去除效率。基于他们更好的H 2S处理性能和较低的材料成本,选择LCS和SS304进行中试规模测试。在为期92天的操作中,中试规模的演示表明,LCS和SS304的H 2 S去除效率分别为84.0%和63.5%。技术经济评估表明,使用LCS作为电极,电化学系统的安装和运行费用占谷仓建设成本的16%。进一步的优化可以大大减少电极材料的消耗和总体成本。

更新日期:2021-03-04
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