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Integration of RuO2/conductive fiber composites within carbonized micro-electrode array for supercapacitors
Journal of Alloys and Compounds ( IF 5.8 ) Pub Date : 2021-02-24 , DOI: 10.1016/j.jallcom.2021.159300
Mao-Jung Huang , Wen-Hsi Chen , Chia Cheng , Shin-Rung Chen , Jeng-Yu Lin , Chii-Rong Yang

This study employed a carbon microelectromechanical system (C-MEMS) in fabricating a 3D micro-electrode array of conductive carbon cylinders directly on the surface of a graphite substrate. The capacitance of the array was further enhanced by decorating it with a composite material comprising highly-porous carbon nanofibers (CF) and electroactive RuO2 nanoparticles to function as an active electrode. In galvanostatic charge-discharge tests, the specific capacitance of an electrode decorated with RuO2 30 wt%/CF was 219.2 F g−1 at a current density of 0.5 A g−1, which is 2.27 times higher than that of the pristine CF electrode. When the current density was increased from 0.5 A g−1 to 3 A g−1, the capacitance retention of the RuO2 30 wt%/CF electrode was 54.8%. A symmetric supercapacitor based on the RuO2 30 wt%/CF composite electrode exhibited an impressive energy density of 74.2 Wh kg−1 with power density of 4333 W kg−1. It also demonstrated good capacitance retention of 80.2% following 3000 consecutive charge/discharge cycles at a current density of 2 A g−1.



中文翻译:

RuO 2 /导电纤维复合材料在超级电容器碳化微电极阵列中的集成

这项研究采用碳微机电系统(C-MEMS)直接在石墨基板的表面上制造了导电碳圆柱的3D微电极阵列。通过用包含高孔碳纳米纤维(CF)和电活性RuO 2纳米颗粒的复合材料装饰它作为有源电极,可以进一步提高该阵列的电容。在恒电流充放电试验中,装饰用RuO的电极的比电容2 30%(重量)/ CF为219.2 F G -1以0.5 g的电流密度-1,它比原始CF的2.27倍电极。当电流密度从0.5 A g -1增加到3 A g -1时,RuO 2 30wt%/ CF电极的电容保持率为54.8%。基于RuO 2 30 wt%/ CF复合电极的对称超级电容器展现出令人印象深刻的74.2 Wh kg -1的能量密度和4333 W kg -1的功率密度。在电流密度为2 A g -1的情况下,经过3000次连续的充电/放电循环,还显示出80.2%的良好电容保持率。

更新日期:2021-03-02
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