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Generation of circular dichroism from superposed porphyrin films
Chirality ( IF 2.8 ) Pub Date : 2021-02-23 , DOI: 10.1002/chir.23302 Hideaki Takechi 1 , Hitoshi Watarai 2
Chirality ( IF 2.8 ) Pub Date : 2021-02-23 , DOI: 10.1002/chir.23302 Hideaki Takechi 1 , Hitoshi Watarai 2
Affiliation
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Circular dichroism (CD) was observed from the superposed porphyrin deposited glass plates, which were prepared by the vapor deposition of achiral porphyrin molecules and oriented to one direction by rubbing parallel to the surface of plate. The CD spectra depended on the twisted angle between the plates and the number of plates superposed. The observed CD spectra agreed with the simulated ones by the Mueller matrices superposition calculation using the observed linear dichroism spectra and linear birefringence spectra of each plate.
中文翻译：
从叠加的卟啉薄膜中产生圆二色性
从重叠的卟啉沉积玻璃板观察到圆二色性（CD），该玻璃板是通过非手性卟啉分子的气相沉积制备的，并且通过平行于板表面的摩擦而沿一个方向取向。CD光谱取决于板之间的扭曲角和叠置的板数。通过观察Mueller矩阵叠加计算，使用观察到的每个板的线性二色性光谱和线性双折射光谱，观察到的CD光谱与模拟的CD光谱一致。
更新日期：2021-04-08
中文翻译：
从叠加的卟啉薄膜中产生圆二色性
从重叠的卟啉沉积玻璃板观察到圆二色性（CD），该玻璃板是通过非手性卟啉分子的气相沉积制备的，并且通过平行于板表面的摩擦而沿一个方向取向。CD光谱取决于板之间的扭曲角和叠置的板数。通过观察Mueller矩阵叠加计算，使用观察到的每个板的线性二色性光谱和线性双折射光谱，观察到的CD光谱与模拟的CD光谱一致。
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